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HomeMy WebLinkAboutPR 23142: PURCHASE OF SODIUM CHLORITE ( Ciry l Energ rt rthu � www.PortArthurTx.gov INTEROFFICE MEMORANDUM Date: April 28, 2023 To: The Honorable Mayor and City Council Through: Ronald Burton, City Manager From: Calvin Matthews, P.E., Water Utilities Director RE: PR No. 23142 - Purchase of Sodium Chlorite Introduction: The intent of this Agenda Item is to seek the City Council's approval for the City Manager to enter into a six (6)month contract with Evoqua Water Technologies, LLC, of Sarasota, Florida, for the purchase of Sodium Chlorite with the option to renew for six (6) more months. Background: Sodium Chlorite is used at our Water Purification Plant to make Chlorine Dioxide for the disinfection and treatment of drinking water. Bids were solicited from qualified bidders as delineated in the City of Port Arthur Purchasing Policy. Evoqua was the lowest bid received on April 14, 2023. Budget Impact: Based on previous chemical usage at the Water Purification Plant, Staff believes we will use no more than 600,000 lbs of Sodium Chlorite in a one (1) year period. The price per pound from Evoqua was $0.85/lb., for an annual projected budgetary impact of$510,000.00. This amount has been budgeted in Water Utilities Account No. 410-40-210-5217-00-00-000, Treatment Chemicals. Recommendation: It is recommended that City Council approve PR No. 23142, authorizing the City Manager to enter into a contract with Evoqua Water Technologies, LLC, of Sarasota, Florida as discussed/outlined above. "Remember,we are here to serve the Citizens of Port Arthur" P.O.Box 1089 X Port Arthur,Texas 77641-1089 X 409.983.8101 X FAX 409.982.6743 PR No. 23142 4/28/23 bw Page 1 of 2 RESOLUTION NO. A RESOLUTION AUTHORIZING THE CITY MANAGER TO ENTER INTO A SIX (6) MONTH CONTRACT WITH EVOQUA WATER TECHNOLOGIES OF SARASOTA, FLORIDA FOR THE PURCHASE OF SODIUM CHLORITE FOR THE WATER UTILITIES DEPARTMENT WITH THE OPTION TO RENEW FOR AN ADDITIONAL SIX (6) MONTHS, WITH AN ANNUAL PROJECTED BUDGETARY IMPACT OF$510,000.00.FUNDING IS AVAILABLE IN ACCOUNT NO. 410-40-210-5217-00-00-000, TREATMENT CHEMICALS. WHEREAS,sodium chlorite is used at the City's Water Purification Plant for the disinfection and treatment of drinking water; and, WHEREAS, on April 1, 2023 and April 5, 2023, the City advertised for bid proposals for sodium chlorite and received two (2)bids on April 14, 2023 (Exhibit"A"); and, WHEREAS, Evoqua Water Technologies of Sarasota, Florida, was the lowest most responsible bid; and. WHEREAS, this contract is for six months with an option to renew for an additional six months period; and, NOW THEREFORE,BE IT RESOLVED BY THE CITY COUNCIL OF THE CITY OF PORT ARTHUR: THAT, the City Manager is hereby authorized to execute a six-month contract for sodium chlorite for water disinfection with Evoqua Water Technologies of Sarasota,Florida,with an option to renew for an additional six months, with a projected budgetary impact of $510,000.00, attached in substantially the same form as Exhibit"B"; and, THAT, funding is available in Account No. 410-40-210-5217-00-00-000, Treatment Chemicals; and, THAT, a copy of the caption of this Resolution be spread upon the Minutes of the City Council. PR No. 23142 4/28/23 bw Page 2 of 2 READ, ADOPTED, AND APPROVED on this day of , 2023 at a Regular Meeting of the City Council of the City of Port Arthur, Texas, by the following vote: AYES: Mayor: Councilmembers: NOES: Thurman Bill Bartie Mayor ATTEST: APPROVED AS TO FORM: Sherri Bellard Val Tizeno City Secretary City Attorney APPROVED FOR ADMINISTRATION: APPROVED AS TO THE AVAILABILITY OF FUNDS KL--01 Ronald Burton Kandy D Cit ger Finance D. ector (1e0 -e 01 4' alvin atthews, P.E. Cl_fton Williams, CPPB Water Utilities Director Purchasing Manager Exhibit A 0 cn o 0 c U o O o w) - d cn cu a Z I o 4 a o V a U o, z M C D C2 Np O vl c-0 N V 4 - O .� O CU , w U o 5 as W a cl o O x M .� y e� V� nl E) >- 00• ^C it C © C� C V 3 0 ,� A 0, p Co)C.) G C C EoS a ^O v >> .4 . bt 45 d .a °' •.w ° E4 o wo o a VI W O' o °' o Zi. o J G U O .41) Ez:.. 45. = t:, 5 ::,..l70 o p i r Exhibit B PURCHASING CONTRACT AGREEMENT Sodium Chlorite THIS AGREEMENT is made this the of , 2023, by and between an individual, firm, partnership, or corporation, Evoqua Water Technologies of Sarasota, Florida hereinafter called "Vendor", and the City of Port Arthur, a municipal corporation organized under the laws of the State of Texas, hereinafter called the "Owner" or "City". WITNESSETH: That for and in consideration of the payments, terms, conditions and agreements set forth herein, Owner and Vendor agree as follows: 1. This Agreement is from , 2023 to , 2023 with the option to renew for six additional months. 2. The City can terminate this contract at its convenience which includes, but not limited to, funding not being available in any budget cycle with thirty (30) days written notice. 3. During the term of this Contract, the Vendor will furnish all of the materials and supplies, as stated in the specifications, described as: Sodium Chlorite 4. The CONTRACTOR agrees to perform all the work described in the specifications and contract documents and to comply with the terms therein for the cost per bid dated April 14, 2023. DESCRIPTION Unit Cost Sodium Chlorite $0.85 Per lbs. 5. The term "Contract Documents" means and includes the following: 1) Agreement 2) General Information 3) Specification 4) Addendum 5) Bid 6) Notice of Award 7) Notice to Proceed 6. This Agreement shall be binding upon all parties hereto and their respective heirs, executors, administrators, successors and assigns. IN WITNESS WHEREOF, the parties hereto have executed, or caused to be executed by their duly authorized officials, this Agreement in two (2) copies each of which shall be deemed an original on the date first above written. SIGNED AND AGREED to on the day of , 2023. WITNESS: CONTRACTOR: Evoqua Water Technologies SIGNED AND AGREED to on the day of , 2023. ATTEST: CITY OF PORT ARTHUR: Sherri Bellard Ronald Burton City Secretary City Manager O9;1W CITY OF PORT ARTHUR, TEXAS COPY o rt ADDENDUM NO. ONE (1) April 5, 2023 BID FOR: SODIUM CHLORITE The following clarifications, amendments, deletions, additions, revision and/or modifications are made a part of the contract documents and change the original documents only in the manner and to the extent hereinafter stated and shall be incorporated in the contract documents. Provisions of this addendum shall take precedence over requirements of the original contract documents and all BIDDERS ARE REQUESTED TO ACKNOWLEDGE SAID PROVISIONS IN THE SUBMISSION OF THEIR BID. Addendum as follows: 1. DEADLINE: Sealed Bid submittals must be received and time stamped by 3:00 p.m., Central Standard Time, Friday, April 14, 2023 (The clock located in the City Secretary's office will be the official time.) All bids received will be read aloud at 3:15 p.m. on Friday, April 14, 2023 in the City Council Chambers, City Hall, 5th Floor, Port Arthur, TX. You are invited to attend. If you have any questions,please contact the Purchasing Division at 409-983-8160. NOTE: ALL PAGES OF ADDENDA MUST BE SIGNED AND SUBMITTED WITH YOUR BID DOCUMENTS. Cli'f, Williams,CPPB Purchasing Manager 04/10/2023 Signature of Proposer Date .\ 1 THURMAN BILL BARTIE,MAYOR RONALD BURTON INGRID HOLMES,MAYOR PRO TEM Energy CITY MANAGER City of City COUNCIL MEMBERS: �1 SHERRI BELLARD,TRMC CAL JONES 40.1 CITY SECRETARY THOMAS KINLAW III �� t r 1 l t[ � KENNETH MARKS VAL TIZENO CHARLOTTE MOSES Tezas CITY ATTORNEY DONALD FRANK,SR. APRIL 1,2023 INVITATION TO BID PURCHASE OF SODIUM CHLORITE DEADLINE: Sealed Bid submittals must be received and time stamped by 3:00 p.m., Central Standard Time, Wednesday, April 12, 2023 (The clock located in the City Secretary's office will be the official time.) All bids received will be read aloud at 3:15 p.m. on Wednesday, April 12, 2023 in the City Council Chambers, City Hall, 5th Floor,Port Arthur, TX. You are invited to attend. MARK ENVELOPE:P23-041 DELIVERY ADDRESS: Please submit one(1) original and one (1) copy of your bid to: CITY OF PORT ARTHUR CITY OF PORT ARTHUR CITY SECRETARY or CITY SECRETARY P.O. BOX 1089 444 4TH STREET,4th Floor PORT ARTHUR, TEXAS 77641 PORT ARTHUR, TEXAS 77640 POINTS OF CONTACT: Questions concerning the Invitation to Bid or Scope of Work should be directed in writin,to: City of Port Arthur, TX Clifton Williams, Purchasing Manager P.O. Box 1089 Port Arthur, TX 77641 clifton.williamsna,portarthurtx.gov The enclosed Invitation to Bid(ITB) and accompanying General Instructions, Conditions and Specifications are for your convenience in submitting bids for the enclosed referenced services for the City of Port Arthur. Bids must be signed by a person having authority to bind the firm in a contract. Bids shall be placed in a sealed envelope, with the Vendor's name and address in the upper left-hand corner of the envelope. ALL BIDS MUST BE RECEIVED IN THE CITY SECRETARY'S OFFICE BEFORE OPENING DATE AND TIME. It is the sole responsibility of the firm to ensure that the sealed ITB submittal arrives at the above location by specified deadline regardless of delivery method chosen by the firm. Faxed or electronically transmitted ITB submittals will not be accepted. Clifton Williams, CPPB Purchasing Manager Page2of19 INVITATION TO BID PURCHASE OF SODIUM CHLORITE (To be Completed ONLY IF YOU DO NOT BID) FAILURE TO RESPOND TO BID SOLICITATIONS FOR TWO (2) BID PERIODS MAY RESULT IN REMOVAL FROM THE VENDOR'S LIST. However, if you are removed you will be reinstated upon request. In the event you desire not to submit a bid, we would appreciate your response regarding the reason(s). Your assistance in completing and returning this form in an envelope marked with the enclosed bid would be appreciated. NO BID is submitted: this time only not this commodity/service only Yes No Does your company provide this product or services? Were the specifications clear? Were the specifications too restrictive? Does the City pay its bills on time? Do you desire to remain on the bid list for this product or service? Does your present work load permit additional work? Comments/Other Suggestions: Company Name: Person Completing Form: Telephone: Mailing Address: Email: City,State, Zip Code: Date: Page 3 of 19 SUBMIT THE FOLLOWING. A. BID SHEETS-PAGE 7 B. EQUIPMENT LIST-8 C. NON-COLLUSION AFFIDAVIT-PAGE 9 (MUST BE NOTARIZED) D. AFFIDAVIT-PAGE 10 (MUST BE NOTARIZED) E. CONFLICT OF INTEREST-(IF NO CONFLICT WRITE N/A OR NOT APPLICABLE ON LINE 1 AND SIGN&DATE ON LINE 7-PAGE 11 F. CHAPTER 2252 CERTIFICATION-PAGE 13 G. HOUSE BILL 89 VERIFICATION-PAGE 14 Page 4 of 19 CITY OF PORT ARTHUR, TEXAS SPECIFICATIONS FOR A TWO(2) YEAR SERVICE CONTRACT TO PROVIDE CHLORINE DIOXIDE GENERAL DESCRIPTION Bids are being accepted for a service contract to purchase sodium chlorite to produce chlorine dioxide. The chlorine dioxide shall be generated onsite for use as a disinfectant. The chlorine dioxide system shall be installed at the City of Port Arthur's water treatment plant. The treatment plant treats surface water from the Lower Neches Valley Authority for drinking water. The average daily flow of the treatment plant is approximately 16.0 mgd with a maximum of 40 mgd. The C102 dosage rate of the equipment must be variable from 0.25 mg/1 to 3.0 mg/1 (ppm) at the desired plant flow rates without loss of generator efficiency. It is estimated that we will need about 500,000 pounds per year of sodium chlorite. Bidder shall supply a list of at least four systems including names and telephone numbers of facilities wherein they have installed and are currently servicing chlorine dioxide systems. The system which is bid must be CURRENTLY accepted by all applicable regulatory agencies including the Texas Commission on Environmental Quality. SPECIFICATIONS A. The successful bidder shall supply a system for generating CHLORINE DIOXIDE as an aqueous solution from the reaction of SODIUM CHLORITE and CHLORINE GAS, the 3 units shall be capable of delivering the required amount of C102 at each feed point on a continuous basis, 24 hours a day, to meet the CT and TTHM requirements set by the EPA and TCEQ. B. The 3 units shall be properly sized, and designed specifically for the intended application set forth in the general description above. The unit shall be equipped with a Siemens non contact magnetic flow measuring device and stream pH measuring device with 4-20 mA output signal to assist in maintaining system efficiency, and to prevent waste of plant water. Shall be equipped with loss of chlorine and/or water feed automatic shutdown. A fully equipped standby unit shall be provided. The unit shall not require pH measurement or adjustment for operation. Each unit shall be provided with necessary devices to manually adjust the chlorine dioxide feed rate to provide means to accurately split clo2 into 4 separate injection points with each generator capable of supplying at least 2 injection points and each capable of supplying any 2 of the 4 points. C. The reaction product purity shall not be less than 95 percent C102, and the total by-products must remain lower than 1.0 mg/1(PPM), for chlorite in the distribution system at the approved sample locations at all times. D. Bidder shall supply all equipment and materials necessary to generate the solution onsite. Bidder must furnish a device for equally splitting the chlorine dioxide into two different injection points. Except for electricity, plant water at system pressure, and chlorine gas, All equipment and materials furnished shall be suitable for the application specified, and shall comply with all Federal, State, and Local codes, laws, and ordinances. Generator chlorine and sodium chlorite feedrates must be manually adjustable E. The bidder's SODIUM CHLORITE solution must be approved and registered with the ENVIRONMENTAL PROTECTION AGENCY (EPA) and/or NSF for use in potable water systems. Bidder's own EPA registration number must be included in the bid package. The solution shall conform to: Page 5 of 19 Active Ingredient: 25% (+/-1.0%by wt.)NaC102 Inert Ingredient: 75% (+/-1.0%by wt.)H2O Appearance: Pale yellow slightly hazy liquid Shelf Life: One (1)year, minimum Product Bulletins and Material Safety Data Sheets must be included in the bid package. F. Bidder shall supply, install, and maintain 2 heavy-duty chemical storage tank of at least 6,200 gallon capacity for receiving, storing, and dispensing sodium chlorite to a tank that is transparent or has a sight gauge for determining the level. Transfer pumps, at least two, shall be provided to transfer the sodium chlorite from the bulk tanks to the day tank. Bidder shall provide signage and warning of hazards in the storage and generation areas. G. Deliveries of sodium chlorite shall be via dedicated bulk trucks. If trucks are not Bidder operated, a Bidder's trained employee shall supervise all deliveries. ALL SPILLS AND LEAKAGE, REGARDLESS OF SIZE, SHALL BE PROPERLY AND IMMEDIATELY CLEANED UP BY BIDDER'S PERSONNEL. H. Prior to installation of the system, bidder shall deliver a complete and detailed installation and operations manual, including illustrations and drawings, Material Safety Data Sheets, and other hazardous warning information. I. Bidder shall provide all necessary labor and materials for a complete installation. All work will be performed by workmen skilled and experienced in the necessary crafts. J. Bidder shall provide all necessary labor and materials to maintain the system at peak operating efficiency and safety. The bidder shall maintain a complete inventory of spare parts in local stock. All maintenance shall be performed by trained technicians, familiar and experienced with bidder's equipment. SAID TECHNICIAN SHALL BE AVAILABLE 24 HOURS A DAY, 7 DAYS A WEEK, AND SHALL RESPOND AND BE ONSITE WITHIN TWO (2) HOURS ON ANY EMERGENCY. K. He shall bring any and all replacement parts and tools with him on the first response. Bidder shall absorb all repair costs. L. Bidder shall perform routine inspections and preventative maintenance on the system as required, but not to exceed intervals of one (1) month between such inspections and preventative maintenance unless approved by Plant Superintendent or his agent. M. During each inspection, bidder's technician shall: 1. Inspect the entire chlorine dioxide system for leaks and malfunctions. 2. Analyze the generator outputs for percentage of chlorine dioxide in the product stream, free chlorine, unreacted chlorite, chlorate, and pH. (Before making any adjustments) Procedures for this analysis shall be submitted before placing the equipment in service. 3. Analyze water leaving filters, for Total and Free Chlorine,utilizing the amperometric method as outlined in Standard Methods for the Examination of Water and Wastewater, section 4500C or E, also the Chlorine Dioxide residuals at this location. 4. Check sodium chlorite pump output at various flow rates to assure efficiency if used. 5. Review plant control records to ensure maximum generator efficiency. 6. Provide initial or additional training for plant operators as required to maintain proficiency of all involved PERSONNEL. 7. Complete and submit a field service report form detailing items a-f above as a written record of Page6of19 : ,, services provided, and as a formal request for any changes that may be necessary. Bidder shall absorb the cost of the inspection and preventative maintenance program set out above. N. Startup and initial training shall be provided by the bidder at no additional charge, and will include training operating PERSONNEL in the following areas: 1. Checking the equipment installation. 2. Physical properties of chlorine dioxide, chlorine, chlorite, chlorate, and/or any other chemicals used in the system. 3. Chemistry/methods of chlorine dioxide generation. 4. How to optimize generator performance. 5. Maintenance procedures. 6. Safety considerations in operations and chemical handling. 7. Sampling procedure for chlorine dioxide determinations. O. Bidder shall provide the following test, every month during, the life of this agreement. Testing must be performed using an Ion Chromatograph and the procedure listed in Dionex Corporation's Application Note 149. Bidder shall absorb all testing cost. 1. Chlorite analysis (treated water 3 samples). 2. Chlorate analysis (treated water 3 samples if needed). P. Bidder shall provide the following analysis on at least a monthly basis 1. Total organic carbon(if needed). 2. Raw water. 3. Before filters. Q. Contract is six months with the option to renew for an additional six months. R. Bidder shall agree to maintain equipment until product purchased from Bidders Company has been used up and the bidder is released by Plant Superintendent or his agent. S. Delivery of product shall be no more than five (5) days after notification by authorized City PERSONNEL. T. Bidder shall submit bid based on a price per pound of specified sodium chlorite solution. Price bid FOB Port Arthur. U. All bidders will be required to submit proof of qualifications, including references, names of current service PERSONNEL, EPA Registration number for sodium chlorite, laboratory qualifications, Material Safety Data Sheets,written acceptance of State Regulatory officials if account references (or no references are available) are outside of the State, and all other pertinent information related to this bid. V. Successful bidder must have C 102 system operational fifteen(15) days after award of bid. W. Bidder must supply one (1) Amperometric Titrator supplied by Severn Trent Capital Controls with a spare electrode to be installed at the Water Plant. EXCEPTIONS CITY WILL EXCEPT A. The IDI MG2 manual system uses pH to monitor, not control, the proper amount of chlorine. This ensures efficiency of the system across the chlorine dioxide production range specified by IDI, which meets the needs of the water plant as communicated of 11.5-40 MGD and a dose of 1.2-3.0 PPM. Page 7 of 19 B. The system will be equipped with a 2 branch output panel that will require 100% of the generator output flow split equally between both application points. Less than 100% output would increase back pressure and compromise education. C. All deliveries will be supervised by others. Spills are the responsibility of others and should be responded to according to local State & Federal regulations. In the event of a spill, contact should be made with IDI as well. D. Final Electrical connection to generator by plant. All final water and chemical connections will be completed by DuPont. "Final" connections are defined as within 5' of the installed equipment. All water, chemical, and application pipes beyond 5' of the generator are the responsibility of others. Noted in equipment survey that all requirements are in place via the existing installation. E. Monthly service will be provided. Additional service visits may be needed in the event that the chlorine dioxide system has any unforeseen problems, in which a service technician will be dispatched at his/her earliest convenience. F. IDI uses a modified 4500E analytical method to test for CL02, CL02-, and excess chlorine in our generator effluent. We do not provide chlorate readings as the test lends itself to many inaccuracies and can be very subjective. G. Testing of TOC, raw water, and before the filters is not usually required per the water plant. If this was needed, IDI would be willing to send samples to a lab for testing at an additional cost. H. Chlorine dioxide unit will be shipped ASAP after the announcement of the award. Typically, manufacturing of a unit can take 6 to 12 weeks depending on the production queue. I. IDI will supply (1) Amperometric Titrator supplied by Severn Trent Capital Controls, However Customer is responsible for all service, Calibration,reagents and repairs of the unit. CONTRACT TERM The contract shall be six months with the option to renew for an additional six months Page 8 of 19 CITY OF PORT ARTHUR, TEXAS BID SHEET BID FOR: Purchase of Sodium Chlorite BID DUE DATE: April 12, 2023 ITEM# EST. QTY UOM DESCRIPTION UNIT COST TOTAL COST 1 600,000 LBS Sodium Chlorite $ 0.85 $510,000 *Additional $3248.50 for Kemio Kit. See Attachment A. Evoqua Water Technologies LLC 2650 Tallevast Road COMPANY NAME STREET ADDRESS SIG BIDDER P.O.BOX Thomas R. Wilson, P.E. Sarasota FL 34243 PRINT OR TYPE NAME CITY STATE ZIP V.P. & G.M. 941-359-7930 TITLE AREA CODE TELEPHONE NO municipalservices@evoqua.com 941-359-7985 EMAIL FAX NO. Page 9 of 19 eVOQUA WATER TECHNOLOGIES ATTACHMENT A Exceptions 1. Page 6 of 19, Paragraph J: Evoqua shall be available 24 hours a day, 7 days a week and shall respond via telephone within two (2) hours and be onsite within four (4) hours of any emergency. 2. Page 6 of 19, Paragraph M.2: Evoqua has not included Chlorate testing in the field as it is not required by the State of Texas. 3. Page 7 of 19, Paragraph 0.2: Evoqua has not included Chlorate analysis as it is not required by the State of Texas. 4. Page 8 of 19, Paragraph G: Evoqua has not included TOC testing as it is not required. 5. Page 8 of 19, Paragraph I: Evoqua will not be providing an Amperometric Titrator, but will provide a Kemio Kit at the price provided within the bid. 2650 Tallevast Road Tel:+1(888)228-9877 Sarasota,FL 34243 USA Fax:+1 (941)359-7985 www.evoqua.com AFFIDAVIT All pages in Offeror's Responses containing statements, letters, etc., shall be signed by a duly authorized officer of the company whose signature is binding. The undersigned offers and agrees to one of the following: X I hereby certify that I do not have outstanding debts with the City of Port Arthur. I further agree to pay succeeding debts as they become due. I hereby certify that I do have outstanding debts with the City of Port Arthur and agree to pay said debts prior to execution of this agreement. I further agree to pay succeeding debts as they become due. I hereby certify that I do have outstanding debts with the City of Port Arthur and agree to enter into an agreement for the payment of said debts. I further agree to pay succeeding debts as they become due. Evoqua Water Technologies LLC 04/10/2023 Firm Name Date V.P. & G.M. Autho zed Signature Title Thomas R. Wilson, P.E. 941-359-7930 Name (please print) Telephone municipalservices@evoqua.com Email `o- - - * - . irapeopeor Florida : � :. KnnEIGH E.MOww STATE: :,: MY COMMISSION#HH 045434 EXPIRES:September22,2024 COUNTY: Manatee °•"." err Luc Und«wrk�s - r Uw SUBSCRIBED AND SWORN to before me by the above named Thomas R. Wilson,P.E. on this the 10th day of April , 20 23 ` btfCE Ito E.A e N ry Public RETURN THIS AFFIDAVIT AS PART OF THE BID PROPOSAL Page 10 of 19 CONFLICT OF INTEREST QUESTIONNAIRE FORM CIQ For vendor doing business with local governmental entity This questionnaire reflects changes made to the law by H.B. 23, 84th Leg., Regular Session. OFFICE USE ONLY This questionnaire is being filed in accordance with Chapter 176, Local Government Code, by a vendor who Date Received has a business relationship as defined by Section 176.001(1-a) with a local governmental entity and the vendor meets requirements under Section 176.006(a). By law this questionnaire must be filed with the records administrator of the local governmental entity not later than the 7th business day after the date the vendor becomes aware of facts that require the statement to be filed. See Section 176.006(a-1), Local Government Code. A vendor commits an offense if the vendor knowingly violates Section 176.006, Local Government Code.An offense under this section is a misdemeanor. Name of vendor who has a business relationship with local governmental entity. Evoqua Water Technologies LLC ?1n ! I Check this box if you are filing an update to a previously filed questionnaire.(The law requires that you file an updated 1 1 completed questionnaire with the appropriate filing authority not later than the 7th business day after the date on which you became aware that the originally filed questionnaire was incomplete or inaccurate.) Name of local government officer about whom the information is being disclosed. N/A Name of Officer J Describe each employment or other business relationship with the local government officer,or a family member of the officer,as described by Section 176.003(a)(2)(A). Also describe any family relationship with the local government officer. Complete subparts A and B for each employment or business relationship described. Attach additional pages to this Form CIO as necessary. A. Is the local government officer or a family member of the officer receiving or likely to receive taxable income, other than investment income, from the vendor? Yes No B. Is the vendor receiving or likely to receive taxable income,other than investment income,from or at the direction of the local government officer or a family member of the officer AND the taxable income is not received from the local governmental entity? Yes No Describe each employment or business relationship that the vendor named in Section 1 maintains with a corporation or other business entity with respect to which the local government officer serves as an officer or director, or holds an ownership interest of one percent or more. fl Check this box if the vendor has given the local government officer or a family member of the officer one or more gifts as described in Section 17 .003(a)(2)(B), excluding gifts described in Section 176.003(a-1). 04/10/2 07 3 Sign re of vendor doing business Te goVemmental entity Date Form provided by Texas Ethics Commission www.ethics.state.tx.us Revised 11/30/2015 Page 11 of 19 CONFLICT OF INTEREST QUESTIONNAIRE For vendor doing business with local governmental entity Acomplete copy of Chapter 176 of the Local Government Code may be found at http://www.statutes.legis.state.tx.us/ Docs/LG/htm/LG.176.htm.For easy reference,below are some of the sections cited on this form. Local Government Code§176.001(1-a):"Business relationship"means a connection between two or more parties based on commercial activity of one of the parties. The term does not include a connection based on: (A) a transaction that is subject to rate or fee regulation by a federal,state,or local governmental entity or an agency of a federal,state,or local governmental entity; (B) a transaction conducted at a price and subject to terms available to the public;or (C) a purchase or lease of goods or services from a person that is chartered by a state or federal agency and that is subject to regular examination by,and reporting to,that agency. Local Government Code§176.003(a)(2)(A)and(B): (a) A local government officer shall file a conflicts disclosure statement with respect to a vendor if: (2) the vendor: (A) has an employment or other business relationship with the local government officer or a family member of the officer that results in the officer or family member receiving taxable income, other than investment income, that exceeds$2,500 during the 12-month period preceding the date that the officer becomes aware that (i) a contract between the local governmental entity and vendor has been executed; or (ii) the local governmental entity is considering entering into a contract with the vendor; (B) has given to the local government officer or a family member of the officer one or more gifts that have an aggregate value of more than$100 in the 12-month period preceding the date the officer becomes aware that: (i) a contract between the local governmental entity and vendor has been executed;or (ii) the local governmental entity is considering entering into a contract with the vendor. Local Government Code§176.006(a)and(a-1) (a) A vendor shall file a completed conflict of interest questionnaire if the vendor has a business relationship with a local governmental entity and: (1) has an employment or other business relationship with a local government officer of that local governmental entity,or a family member of the officer,described by Section 176.003(a)(2)(A); (2) has given a local government officer of that local governmental entity,or a family member of the officer,one or more gifts with the aggregate value specified by Section 176.003(a)(2)(B),excluding any gift described by Section 176.003(a-1);or (3) has a family relationship with a local government officer of that local governmental entity. (a-1) The completed conflict of interest questionnaire must be filed with the appropriate records administrator not later than the seventh business day after the later of: (1) the date that the vendor: (A) begins discussions or negotiations to enter into a contract with the local governmental entity;or (B) submits to the local governmental entity an application,response to a request for proposals or bids, correspondence, or another writing related to a potential contract with the local governmental entity;or (2) the date the vendor becomes aware: (A) of an employment or other business relationship with a local government officer,or a family member of the officer,described by Subsection(a); (B) that the vendor has given one or more gifts described by Subsection(a);or (C) of a family relationship with a local government officer. Form provided by Texas Ethics Commission www.ethlcs state.tx.us Revised 11/30/2015 Page 12 of 19 SB 252 CHAPTER 2252 CERTIFICATION I, Thomas R. Wilson,P.E. ,the undersigned and representative of Evoqua Water Technologies LLC (Company or Business Name) being an adult over the age of eighteen (18) years of age, pursuant to Texas Government Code, Chapter 2252, Section 2252.152 and Section 2252.153,certify that the company named above is not listed on the website of the Comptroller of the State of Texas concerning the listing of companies that are identified under Section 806.051, Section 807.051 or Section 2253.153. I further certify that should the above-named company enter into a contract that is on said listing of companies on the website of the Comptroller of the State of Texas which do business with Iran, Sudan or any Foreign Terrorist Organization, I will immediately notify the City of Port Arthur Purchasing Department. Thomas R. Wilson, P.E. Name of Company Representative (Print) Signature C mpany Representative 04/10/2023 Date Page 13 of 19 House Bill 89 Verification I, Thomas R. Wilson, P.E. (Person name), the undersigned representative (hereafter referred to as "Representative") of Evoqua Water Technologies LLC (company or business name, hereafter referred to as "Business Entity"), being an adult over the age of eighteen (18) years of age, after being duly sworn by the undersigned notary, do hereby depose and affirm the following: 1. That Representative is authorized to execute this verification on behalf of Business Entity; 2. That Business Entity does not boycott Israel and will not boycott Israel during the term of any contract that will be entered into between Business Entity and the City of Port Arthur; and 3. That Representative understands that the term "boycott Israel" is defined by Texas Government Code Section 2270.001 to mean refusing to deal with, terminating business activities with, or otherwise taking any action that is intended to penalize, inflict economic harm on, or limit commercial relations specifically with Israel, or with a person or entity doing business in Israel or in an Israeli-controlled territory, but does not include an action made for ordinary business purposes. SI NATURE OF REP ATIVE Thomas R. Wilson, P.E. SUBSCRIBED AND SWORN TO BEFORE ME, the undersigned authority, on this 10th day of April , 2023 . V �`�.� t iVi LEZCtI E Public virstra .""�+ KAYLEUGH E.MORAN 1„.1 •' ;.: MY COMMISSION It Hit 045434 -:;�-a; EXPIRES:Sept9mber 22,2024 4 '••".21 iti°,.•' Bonded Thar Notary Pubic Underwrkers Page 14 of 19 GENERAL INFORMATION: NOTE: It is extremely important that the Vendor, Bidder, and/or Contractor furnish the City of Port Arthur the required information specified in Bid or Proposal Specifications listed in this Bid Package. All bids meeting the intent of this request for bid will be considered for award. BIDDERS TAKING EXCEPTION TO THE SPECIFICATIONS, OR OFFERING SUBSTITUTIONS, SHALL STATE THESE EXCEPTIONS BY ATTACHMENT AS PART OF THE BID. The absence of such a list shall indicate that the bidder has not taken exceptions and the City shall hold the bidder responsible to perform in strict accordance with the specifications of the invitation. The City reserves the right to accept any and all or none of the exception(s)/substitutions(s) deemed to be in the best interest of the City of Port Arthur. ALTERING BIDS: Bids cannot be altered or amended after submission deadline. Any interlineations, alteration, or erasure made before opening time must be initialed by the signer of the bid, guaranteeing authenticity. BID AWARD: The City of Port Arthur will review all bids for responsiveness and compliance with these specifications. The award shall be made to the responsive,responsible bidder who submits the best value bid. The City reserves the right to: 1. Reject any and all bids and to make no award if it deems such action to be in its best interest. 2. Award bids on the lump sum or unit price basis,whichever is in the best interest of the City. 3. Reject any or all bids and to waive informalities or defects in bids or to accept such bids as it shall deem to be in the best interests of the City. 4. Award bids to bidders whose principal place of business is in the City of Port Arthur and whose bid is within 5%of the lowest bid price, as provided by Section 271.905 of the Texas Government Code. Excluding Federal Funds TERMINOLOGY: "Bid" vs. "Proposal"--For the purpose of this ITB, the terms "Bid" and Proposal" shall be equivalent. Bidders are cautioned to read the information contained in this ITB carefully and to submit a complete response to all requirements and questions as directed. CONFLICT OF INTEREST: Provide a completed copy of the Conflict of Interest Questionnaire (Form CIQ). The Texas legislature recently enacted House Bill 914 which added Chapter 176 to the Texas Local Government Code. Chapter 176 mandates the public disclosure of certain information concerning persons doing business or seeking to do business with the City of Port Arthur, including affiliations and business and financial relationships such persons may have with City of Port Arthur officers. The form can be can be located at the Texas Ethics Commission website: https://www.ethics.state.tx.us/filinginfo/conflict forms.htm By doing business or seeking to do business with the City of Port Arthur including submitting a response to this RFP, you acknowledge that you have been notified of the requirements of Chapter 176 of the Texas Local Government Code and you are representing that you in compliance with them. Any information provided by the City of Port Arthur is for information purposes only. If you have concerns about whether Chapter 176 of the Texas Local Government Code applies to you or the manner in which you must comply,you should consult an attorney. Page 15 of 19 ETHICS: Public employees must discharge their duties impartially so as to assure fair, competitive access to governmental procurement by responsible contractors. Moreover, they should conduct themselves in such a manner as to foster public confidence in the integrity of the City of Port Arthur's procurement organization. Any employee that makes purchases for the City is an agent of the City and is required to follow the City's Code of Ethics. MINIMUM STANDARDS FOR RESPONSIBLE PROSPECTIVE BIDDERS: A prospective bidder must affirmatively demonstrate bidder's responsibility. A prospective bidder must meet the following requirements: 1. Be able to comply with the required or proposed delivery schedule. 2. Have a satisfactory record of performance. 3. Have a satisfactory record of integrity and ethics. 4. Be otherwise qualified and eligible to receive an award. 5. Be engaged in a full time business and can assume liabilities for any performance or warranty service required. 6. The City Council shall not award a contract to a company that is in arrears in its obligations to the City. 7. No payments shall be made to any person of public monies under any contract by the City with such person until such person has paid all obligations and debts owed to the City, or has made satisfactory arrangements to pay the same. ADDENDA: Any interpretations, corrections or changes to the ITB and Specifications will be made by addenda. Sole issuing authority of addenda shall be vested in the City of Port Arthur Purchasing Manager. The City assumes no responsibility for the bidder's failure to obtain and/or properly submit any addendum. Failure to acknowledge and submit any addendum may be cause for the bid to be rejected. It is the vendor's responsibility to check for any addendums that might have been issued before bid closing date and time. PORT ARTHUR PRINCIPAL PLACE OF BUSINESS: Any bona fide business that claims the City of Port Arthur as its principal place of business must have an official business address (office location and office personnel) in Port Arthur, the principal storage place or facility for the equipment shall be in Port Arthur and/or the place of domicile for the principal business owner(s) shall be in Port Arthur or such other definition or interpretation as is provided by state law. Contractors outside the City of Port Arthur are allowed to bid. PRICES: The bidder should show in the proposal both the unit price and total amount,where required, of each item listed. In the event of error or discrepancy in the mathematics, the unit price shall prevail. PURCHASE ORDER: A purchase order(s) shall be generated by the City of Port Arthur to the successful bidder. The purchase order number must appear on all itemized invoices. INVOICES: All invoices shall be mailed directly to the City of Port Arthur, Attn.: Accounts Payable,P.O. Box 1089, Port Arthur, Texas 77641. PAYMENT: Payment will be made upon receipt of the original invoice and the acceptance of the goods or services by the City of Port Arthur, in accordance with the State of Texas Prompt Payment Act, Article 601f V.T.C.S. The City's standard payment terms are net 30, i.e. payment is due 30 days from the date of the invoice. SALES TAX: The City of Port Arthur is exempt by law from payment of Texas Sales Tax and Federal Excise Tax; therefore the proposal shall not include Sales Tax. VENUE: This agreement will be governed and construed according to the laws of the State of Texas. This agreement is performable in Port Arthur, Texas, Jefferson County. Page 16 of 19 COMPLIANCE WITH LAWS: The Contractor shall comply with all applicable laws, ordinances, rules, orders, regulations and codes of the federal, state and local governments relating to performance of work herein. INTEREST OF MEMBERS OF CITY: No member of the governing body of the City, and no other officer, employee or agent of the City who exercises any functions or responsibilities in connection with the planning and carrying out of the program, shall have any personal financial interest, direct or indirect, in this Contract; and,the Contractor shall take appropriate steps to assure compliance. DELINQUENT PAYMENTS DUE CITY: The City of Port Arthur Code of Ordinances prohibits the City from granting any license, privilege or paying money to any-one owing delinquent taxes,paving assessments or any money to the City until such debts are paid or until satisfactory arrangements for payment has been made. Bidders must complete and sign the AFFIDAVIT included as part of this ITB. QUANTITIES: Quantities shown are estimated, based on projected use. It is specifically understood and agreed that these quantities are approximate and any additional quantities will be paid for at the quoted price. It is further understood that the contractor shall not have any claim against the City of Port Arthur for quantities less than the estimated amount. SHIPPING INFORMATION: All bids are to be F.O.B., City of Port Arthur, Port Arthur, TX 77640 INCORPORATION OF PROVISIONS REQUIRED BY LAW: Each provision and clause required by law to be inserted into the Contract shall be deemed to be enacted herein and the Contract shall be read and enforced as though each were included herein. If, through mistake or otherwise, any such provision is not inserted or is not correctly inserted the Contract shall be amended to make such insertion on application by either party. CONTRACTOR'S OBLIGATIONS: The Contractor shall and will, in good workmanlike manner,perform all work and furnish all supplies and materials, machinery, equipment, facilities and means, except as herein otherwise expressly specified, necessary or proper to perform and complete all the work required by this Contract, in accordance with the provisions of this Contract and said specifications. The apparent silence of these specifications as to any detail or to the apparent omission from it of a detailed description concerning any point shall be regarded as meaning that only the best commercial practices are to prevail. While the purpose of the specifications is to indicate minimum requirements in the way of capability, performance, construction, and other details, its use is not intended to deprive the City of Port Arthur the option of selecting goods which may be considered more suitable for the purpose involved. In the event of conflicts between the written bid proposal and information obtained verbally, the vendor is specifically advised that the written bid proposal will prevail in the determination of the successful bidder. Under the Title VI of the Civil Rights Act of 1964, no person shall, on the grounds of race, color, or national origin, be excluded from participation in, be denied the benefits of, or be subjected to discrimination under any program or activity receiving Federal financial assistance. TERMINATION FOR CAUSE: If, through any cause, the Contractor shall fail to fulfill in a timely and proper manner his obligations under this contract, or if the Contractor shall violate any of the covenants, agreements or stipulations of this contract, the City shall thereupon have the right to terminate this contract by giving written notice to the Contractor of such termination and specifying the effective date thereof, at least fifteen (15) days before the effective date of such termination. Notwithstanding the above, the Contractor shall Page 17 of 19 :yet not be relieved of liability to the City for damages sustained by the City by virtue of any breach of the contract by the Contractor, and the City may withhold any payments to the Contractor for the purpose of set-off until such time as the exact amount of damages due the City from the Contractor is determined. TERMINATION FOR CONVENIENCE: The City may terminate this contract at any time giving at least thirty (30) days notice in writing to the Contractor. If the Contract is terminated by the City as provided herein, the Contractor will be paid for the service that it has performed up to the termination date. If this contract is terminated due to fault of the Contractor, the previous paragraph hereof relative to termination shall apply. RELEASES AND RECEIPTS: The City of Port Arthur before making payments may require the Contractor to furnish releases or receipts for any or all persons performing work and supplying material or service to the Contractor, or any sub-contractors for work under this contract, if this is deemed necessary to protect its interests. CARE OF WORK: The Contractor shall be responsible for all damages to person or property that occurs as a result of his fault or negligence in connection with the work performed until completion and final acceptance by the City. SUB-CONTRACTS: The Contractor shall not execute an agreement with any sub-contractor or permit any sub-contractor to perform any work included in this Contract until he has received from the City of Port Arthur written approval of such agreement. INSURANCE: All insurance must be written by an insurer licensed to conduct business in the State of Texas, unless otherwise permitted by Owner. The Contractor shall, at his own expense,purchase, maintain and keep in force insurance that will protect against injury and/or damages which may arise out of or result from operations under this contract, whether the operations be by himself or by any subcontractor or by anyone directly or indirectly employed by any of them, or by anyone for whose acts any of them may be liable, of the following types and limits 1. Standard Worker's Compensation Insurance: 2. Commercial General Liability occurrence type insurance City of Port Arthur, its officers, agents, and employees must be named as an additional insured): a. Bodily injury $500,000 single limit per occurrence or$500,000 each person/$500,000 per occurrence for contracts of$100,000 or less; or Bodily injury $1,000,000 single limit per occurrence or$500,000 each person/$1,000,000 per occurrence for contracts in excess of$100,000; and, b. Property Damage $100,000 per occurrence regardless of contract amount; and, c. Minimum aggregate policy year limit of$1,000,000 for contracts of $100,000 or less; or,Minimum aggregate policy year limit of$2,000,000 for contracts in excess of$100,000. 3. Commercial Automobile Liability Insurance (Including owned, non-owned and hired vehicles coverage's). a. Minimum combined single limit of$500,000 per occurrence, for bodily injury and property damage. Page 18 of 19 b. If individual limits are provided, minimum limits are $300,000 per person, $500,000 per occurrence for bodily injury and$100,000 per occurrence for property damage. Contractor shall cause Contractor's insurance company or insurance agent to fill in all information required (including names of insurance agency, contractor and insurance companies, and policy numbers, effective dates and expiration dates) and to date and sign and do all other things necessary to complete and make into valid certificates of insurance and pertaining to the above listed items, and before commencing any of the work and within the time otherwise specified, Contractor shall file completed certificates of insurance with the Owner. None of the provisions in said certificate of insurance should be altered or modified in any respect except as herein expressly authorized. Said CERTIFICATE OF INSURANCE Form should contain a provision that coverage afforded under the policies will not be altered, modified or canceled unless at least fifteen (15) days prior written notice has been given to the City of Port Arthur. Contractor shall also file with the City of Port Arthur valid CERTIFICATE OF INSURANCE on like form from or for all Subcontractors and showing the Subcontractor(s) as the Insured. Said completed CERTIFICATE OF INSURANCE Form (s) shall in any event be filed with the City of Port Arthur not more than ten(10)days after execution of this Contract. NOTICE TO PROCEED: Notice to Proceed shall be issued within ten (10) days of the execution of the Contract by OWNER. Should there be any reasons why Notice to Proceed cannot be issued within such period, the time may be extended by mutual agreement between OWNER and CONTRACTOR. CELL PHONE OR PAGER: The Contractor must have a working cell phone or pager available Monday through Friday from 8:00 a.m. to 5:00 p.m. so that the City will be able to contact the contractor. Page 19 of 19 EVOQUA WATER TECHNOLOGIES - TEXAS REFERENCES Sodium Chlorite and Chlorine Dioxide Equipment/ Services Please find below a list of selected Evoqua Water Technologies chlorine dioxide/service customers in the State of Texas. Additional references in Texas can be provided upon request. 1. Brownsville Public Utilities Board Contact: Jose Garza Address: 1255 FM 511, Brownsville, TX 78526 Phone: 956-983-6684 E-Mail: jgarza©brownsville-pub.com Period: 1991 - Present Acceptance: June 8, 2022 Contract: Firm Fixed Price Services: Provide four (4) 150 ppd Millennium III CWS Generators, sodium chlorite supply and service 2. City of Temple Water Utilities Contact: Colton Migura Address: 4820 Parkside Dr. Temple, TX 76502 Phone: (254) 298-5941 Email: cmigura@templetx.gov Period: 2007— Present Acceptance: Feb. 7, 2022 Contract: Firm Fixed Price + Variable Increases Services: Provide two (2) x 500 ppd Millennium III C-Auto Chlorine Dioxide Generators and 1 x 500 ppd CWS Generator, sodium chlorite supply and service. 3. City of McAllen Contact: Mr. Joe Solis, Director Address: 2501 West Expressway 83, McAllen, TX 78503 Phone: (956) 681-1700 Email: joe_solis@mcallen.net Period: 2002— Present Acceptance: Nov. 2022 Services: Provide five (5) Millennium III C-Auto Chlorine Dioxide Generators, Three (3) MIII C- CWS C102 Generators, sodium chlorite supply and service. 4. Brazosport Water Authority Contact: Mr. Ronnie Woodruff, General Manager Address: 1251 FM 2004 Lake Jackson, TX 77556 Phone: (979) 202-2059 Email: rwoodruff(cr�bwawater.orq Period: 2000— Present Acceptance: March 2022 Services: Provide Two (2) MIII C-CWS C102 Generators, sodium chlorite supply and service. Qualifications of Key Personnel: Eric Tello, Field Service Technician, Harlingen, TX (941) 313-0066 Chlorine Dioxide References 2/2 Experience: 1+ years of experience in the application of chlorine dioxide in water treatment. Mr. Tello is in Harlingen, TX and reports to the Cedar Park, TX branch office. Eric has direct experience with the application and service of chlorine dioxide equipment at Agua SUD's water treatment facilities eric.tello@evoqua.com Jeff Wood, Field Project Manager, Bonham, TX (713) 208-6505 Experience: 30+ years of experience in the application of chlorine dioxide in water treatment. Mr. Wood is assigned to the Cedar Park, TX branch office. Jeff has direct experience with application and service of chlorine dioxide equipment at Agua SUD's water treatment facilities. He is involved in all aspects of install, service and technical support of chlorine dioxide applications jeffrey.wood@evoqua.com Jeff Mitchell, Field Service Manager, Weatherford, TX (512) 789-2517 Experience: 15+ years of experience in the application of chlorine dioxide in water treatment. Mr. Mitchell is assigned to the Cedar Park, TX branch office and manages all aspects of field service operations including, but not limited to the scheduling of service visits, equipment repair & maintenance and technical support of chemical feed and data collection equipment jeff.mitchell@evoqua.com Mitch Broach, Technical Sales Representative, Houston, TX (337) 247-6407 Experience: 15+ years of experience in the application of chlorine dioxide in water and oil field water applications. Manages the customer relationship and is the primary contact for Agua SUD david.broach@evoqua.com Evoqua Water Technologies Disinfection Group has been involved with the application of 25% Sodium Chlorite Solution for over thirty (30) years. Evoqua is committed to providing the highest standard of chemical quality and technical services in the industry. AktaKlor 25 (25% sodium chlorite solution) is registered with NSF under NSF/ANSI Standard 60 and meets requirements for AWWA B303-10. EPA Registration Number 21164-6. If you require additional information, please contact us. Local customer support for City of Port Arthur Texas will be primarily provided by Mitch Broach, (Technical Sales Representative) - (337) 247-6407 david.broach@evoqua.com; Eric Tello, (Field Service Technician) - (941) 313-0066 eric.tello@evoqua.com; Jeff Wood (Field Project Manager) — (713) 208-6505 jeffrey.wood@evoqua.com; Jeff Mitchell (Field Service Manager) — (512) 789-2517 jeff.mitchell@evoqua.com; and John Robinson (Regional Sales Manager) — (817) 825-0956 john.robinson@evoqua.com CVO Q UA AFFIDAVIT OF COMPLIANCE Evoqua Water Technologies LLC Sodium Chlorite (AKTA KLOR 25), manufactured by OxyChem (Wichita, KS) complies with A.W.W.A. B303-18 specifications, including purity levels, chemical requirements, and physical requirements. In addition, the National Sanitation Foundation (NSF) International certifies OxyChem's Sodium Chlorite for use in potable drinking water. Akta Klor 25 is made in an ISO 9001:2015 facility located in United States of America. The sodium chlorite manufactured by OxyChem and distributed by Evoqua Water Technologies LLC is used in over 100 public water treatment systems. EPA#: 21164-6 Tho s . Wilson Vice President & General Manager 2650 Tallevast Road Tel:+1 (888)228-9877 Sarasota,FL 34243 USA Fax:+1 (941)359-7985 www.evoqua.com OxyChem® Basic Chemicals Sales Specification Sodium Chlorite (NaClO2) AktaKlor 25 (25% Active Sodium Chlorite) COMPONENT SPECIFICATIONS Sodium Chlorite,wt% as NaC1O2 24.25 -25.75 Sodium Chlorate,wt% as NaC1O3 0.5 max. Sodium Chloride,wt% as NaCI 3.0 max. Total Alkalinity,wt% as NaOH @ pH4 0.5 max. Hydrogen Peroxide,wt% as H202 0.01 max. Water (by difference),wt% 68- 76 TYPICAL PROPERTIES Appearance Clear,slightly yellow liquid Turbidity, NTU 10 max Density,lb/gal©25°C 10.1 Typical properties are listed for information only,and are not to be considered as specification requirements. These items are not analyzed on a routine basis. Product meeting the specification test items will exhibit the listed typical properties. NSF Listed,ANSI/NSF Standard 60 (Wichita,KS/Fairmont City,IL) Meets requirements of ANSI/AWWA B303-18 EPA Reg. No: 21164-6 CONTAINERS: Tank Cars (fiberglass lined)-16,000 gallons Tank Trucks (stainless steel) -3400 gallons Drums -55 Gallon Plastic Drums,565 lbs net OCC non-returnable 330 gallon tote with steel box and plastic bottle Form#: 644 05/2019 "ail" Occidental The information presented herein,while not guaranteed,was prepared by Oid DXY ccental Chemical Corporation technical personnel and is true and accurate to the best of our knowledge.NO WARRANTY ti A subsidiary of Occidental Petroleum Corporation OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE,OR WARRANTY OR GUARANTY OF ANY OTHER KIND,EXPRESS OR IMPLIED,IS MADE REGARDING 14555 Dallas Parkway,Suite 400 PERFORMANCE,SAFETY,SUITABILITY,STABILITY OR OTHERWISE.This information Is Dallas,TX 75254 not intended to be all-inclusive as to the manner and conditions of use,handling,storage, disposal and other factors that may involve other or additional legal,environmental,safety 800-752-5151 or performance considerations,and Occidental Chemical Corporation assumes no liability whatsoever for the use of or reliance upon this information.While our technical personnel will be happy to respond to questions,safe handling and use of the product remains the responsibility of the customer.No suggestions for use are intended as,and nothing herein shall be construed as,a recommendation to infringe any existing patents or to violate any Federal,State,local or foreign laws. Listing Category Search Page I NSF International https://info.nsf.org/Certified/PwsChemicals/Listings.asp?CompanyNa... The Public Health and Safety Organization NSF Product and Service Listings These NSF Official Listings are current as of Monday,November 28,2022 at 12:15 a.m.Eastern Time.Please contact NSF to confirm the status of any Listing,report errors,or make suggestions. Alert:NSF is concerned about fraudulent downloading and manipulation of website text.Always confirm this information by clicking on the below link for the most accurate information:httpi//info.nsf.org/Certified/PwsChemicals /Listings.asp?CompanyName=Occidental&ChemicalName=Sodium+Chlorite& NSF/ANSI/CAN 6o Drinking Water Treatment Chemicals - Health Effects Occidental Chemical Corporation 14555 Dallas Parkway Suite 400 Dallas,TX 75254 United States 972-404-380o Facility: # 2 Sauget, IL Sodium Chlorite[CL] Trade Designation Product Function Max Use Technical Sodium Chlorite Chlorine Dioxide Production 7mg/L [CL] The residual levels of chlorine (hypochlorite ion and hypochlorous acid), chlorine dioxide, chlorate ion, chloramine and disinfection by-products shall be monitored in the finished drinking water to ensure compliance to all applicable regulations. Facility : East St. Louis, IL Sodium Chlorite[i][CL] Trade Designation Product Function Max Use 31%Active Sodium Chlorite Solution Chlorine Dioxide Production 22mg/L Akta Klor 15 Chlorine Dioxide Production 35mg/L Akta Klor 25 Chlorine Dioxide Production 22mg/L 1 of 3 11/28/2022, 10:41 AM Listing Category Search Page I NSF International https://info.nsf.org/Certified/PwsChemicals/Listings.asp?CompanyNa... Akta Klor 37 Chlorine Dioxide Production 14mg/L Akta Klor 7.5 Chlorine Dioxide Production 87mg/L Technical Sodium Chlorite Chlorine Dioxide Production 7mg/L Technical Sodium Chlorite 18.75 Chlorine Dioxide Production 35mg/L Technical Sodium Chlorite 31.25 Chlorine Dioxide Production 22mg/L Technical Sodium Chlorite 50 Chlorine Dioxide Production 14mg/L [1] These products are Certified for use in chlorine dioxide generation. [CL] The residual levels of chlorine (hypochlorite ion and hypochlorous acid), chlorine dioxide, chlorate ion, chloramine and disinfection by-products shall be monitored in the finished drinking water to ensure compliance to all applicable regulations. NOTE: Only products bearing the NSF mark on the product, product packaging, product shipping papers, and/or documentation shipped with the product are Certified. Facility: Fairmont City, IL Sodium Chlorite[i][CL] Trade Designation Product Function Max Use 31%Active Sodium Chlorite Solution Chlorine Dioxide Production 22mg/L Akta Klor 15 Chlorine Dioxide Production 35mg/L Akta Klor 25 Chlorine Dioxide Production 22mg/L Akta Klor 37 Chlorine Dioxide Production 14mg/L Akta Klor 7.5 Chlorine Dioxide Production 87mg/L Technical Sodium Chlorite Chlorine Dioxide Production 7mg/L Technical Sodium Chlorite Solution 18.75 Chlorine Dioxide Production 35mg/L Technical Sodium Chlorite Solution 31.25 Chlorine Dioxide Production 22mg/L Technical Sodium Chlorite Solution 5o Chlorine Dioxide Production 14mg/L [1] These products are certified for use in chlorine dioxide generation. [CL] The residual levels of chlorine (hypochlorite ion and hypochlorous acid), chlorine dioxide, chlorate ion, chloramine and disinfection by-products shall be monitored in the finished drinking water to ensure compliance to all applicable regulations. NOTE: Only products bearing the NSF Mark on the product, product packaging, and/or documentation shipped with the product are Certified. Facility : Wichita, KS Sodium Chlorite[i][CL] Trade Designation Product Function Max Use 2 of 3 11/28/2022, 10:41 AM Listing Category Search Page I NSF International https://info.nsf.org/Certified/PwsChemicals/Listings.asp?CompanyNa... 31%Active Sodium Chlorite Solution Chlorine Dioxide Production 22mg/L Akta Klor 25 Chlorine Dioxide Production 22mg/L Akta Klor 7.5 Chlorine Dioxide Production 87mg/L Technical Sodium Chlorite Chlorine Dioxide Production 7mg/L Technical Sodium Chlorite Solution 18.75 Chlorine Dioxide Production 35mg/L Technical Sodium Chlorite Solution 31.25 Chlorine Dioxide Production 22mg/L Technical Sodium Chlorite Solution 5o Chlorine Dioxide Production 14mg/L [1] These products are certified for use in chlorine dioxide generation. [CL] The residual levels of chlorine (hypochlorite ion and hypochlorous acid), chlorine dioxide, chlorate ion, chloramine and disinfection by-products shall be monitored in the finished drinking water to ensure compliance to all applicable regulations. NOTE: Only products bearing the NSF Mark are NSF Certified. Number of matching Manufacturers is i Number of matching Products is 26 Processing time was o seconds 3 of 3 11/28/2022, 10:41 AM SAFETY DATA SHEET M47030- North America - EN OXY Occidental Chemical Corporation A subsidiary of Occidental Petroleum Corporation AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Company Identification: Occidental Chemical Corporation 14555 Dallas Parkway, Suite 400, Dallas, Texas 75254-4300 24 Hour Emergency Telephone 1-800-733-3665 (USA); CANUTEC (Canada): 1-613-996-6666; CHEMTREC Number: (within USA and Canada): 1-800-424-9300; CHEMTREC (outside USA and Canada): +1 703-527-3887; CHEMTREC Contract No: CCN16186 To Request an SDS: MSDS©oxy.com or 1-972-404-3245 Customer Service: 1-800-752-5151 or 1-972-404-3700 Product Identifier: AKTA KLOR 25 Trade Name: AKTA KLOR 25 Synonyms: 25%Active Sodium Chlorite Solution; Sodium Chlorite Solution; Chlorous Acid, Sodium Salt; Sodium Chlorite Solution Product Use: AKTA KLOR 25 is a registered antimicrobial pesticide (EPA Registration Number: 21164-6). It has numerous uses in potable water, food plant process water, poultry process water, CIP disinfection, oilfield water, white water paper mill systems, and industrial cooling water. Restrictions on Use (United This is a pesticide product; do not use in a pesticide application that is not States): approved by the EPA. EPA Reg. No. 21164-6 (Akta Klor 25). Other Global Restrictions on Not registered as a pesticide in Canada. Do not sell for pesticide uses in Canada. Use: Other restrictions on use based on local, regional, or national regulations may exist and must be determined on a case-by-case basis. Chemical Family: Sodium Chlorite Solution Print date: 01-Sep-2020 1 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev.Date: 01-Sep-2020 Supersedes Date: 2016-12-July SECTION 2. HAZARDS IDENTIFICATION OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). EMERGENCY OVERVIEW: Color: Pale, yellow Physical State: Liquid Appearance: Slightly cloudy Odor: Slight chlorine odor Signal Word: DANGER MAJOR HEALTH HAZARDS: CORROSIVE TO EYES AND SKIN. CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. HARMFUL IF SWALLOWED. MAY CAUSE DAMAGE TO CARDIOVASCULAR SYSTEM; BLOOD; SPLEEN; DIGESTIVE SYSTEM;AND STOMACH THROUGH PROLONGED OR REPEATED EXPSOURE VIA ORAL ROUTE. MAY BE HARMFUL IN CONTACT WITH SKIN. THIS MATERIAL IS A POTENTIAL ENDOCRINE DISRUPTOR. PHYSICAL HAZARDS: MAY BE CORROSIVE TO METALS. OXIDIZING AGENT. MAY INTENSIFY FIRE. Dried material can ignite upon contact with combustibles. AQUATIC TOXICITY: Acute Aquatic Toxicity:Very toxic to aquatic life. Chronic Aquatic Toxicity: Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS: Keep only in original container. Keep away from combustible materials. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not breathe dust, vapor or spray mist. Wash skin and contaminated clothing thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves, protective clothing, eye, and face protection.Avoid release to the environment. ADDITIONAL HAZARD INFORMATION: This material is corrosive and an oxidizer when dry.This material is a more severe corrosive and oxidizer when dry.This material's pH and oxidative action contribute to its health and physical hazards. If not stored in original container; store in a corrosive resistant container with a resistant inner liner. Always package, store,transport and dispose of all waste and contaminated equipment in accordance with all applicable federal, state, and local health and environmental regulations. Do not contaminate with acids, reducing agents, combustible materials, oxidizing materials, hypochlorite, organic solvents and compounds, garbage, dirt, organic matter, household products, chemicals, soap products, paint products, vinegar, beverages, oils, pine oil, dirty rags, sulfur-containing rubber,or any other foreign matter. Print date: 01-Sep-2020 2 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July HAZARD CLASSIFICATION: GHS: PHYSICAL HAZARDS: Oxidizing Liquid -GHS Category 3: May intensify fire; oxidizer May be corrosive to metals GHS: CONTACT HAZARD -SKIN: Category 1 B -Causes severe skin burns and eye damage GHS: CONTACT HAZARD - EYE: Category 1 -Causes serious eye damage GHS: ACUTE TOXICITY-ORAL: Category 4 - Harmful if swallowed GHS: TARGET ORGAN TOXICITY(REPEATED Category 2- May cause damage to blood, spleen, and EXPOSURE): stomach through prolonged or repeated exposure HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): -ACUTE TOXICITY - DERMAL: Category 5(May be harmful in contact with skin) -AQUATIC TOXICITY -ACUTE: Category 1 (Very toxic to aquatic life) -ACQUATIC TOXICITY- CHRONIC: Category 3 (Harmful to aquatic life with long lasting effects) -According to NFPA 400, this material is classified as a Class 2 Oxidizer. Class 2 Oxidizers will increase the burning rate of combustible materials with which they come in contact. In addition, they may cause spontaneous ignition when in contact with a combustible material GHS SYMBOL: Oxidizer, Corrosive, Health hazards, Exclamation mark, Environmental hazard GHS SIGNAL WORD: DANGER GHS HAZARD STATEMENTS: GHS -Physical Hazard Statement(s) • May intensify fire; oxidizer • May be corrosive to metals GHS -Health Hazard Statement(s) - • Harmful if swallowed • Causes severe skin burns and eye damage • May cause damage to blood, spleen, and stomach through prolonged or repeated exposure Additional Hazards-GHS Hazards Not Otherwise Classified (HNOC): • MAY BE HARMFUL IN CONTACT WITH SKIN • ACUTE AQUATIC HAZARD - CATEGORY 1: Very toxic to aquatic life • CHRONIC AQUATIC HAZARD- CATEGORY 3: Harmful to aquatic life with long lasting effects GHS -Precautionary Statement(s) - Prevention Print date: 01-Sep-2020 3 of 21 M47030 - North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking • Keep away from combustible materials • Keep only in original container • Do not breathe mist, vapors, or spray • Wash skin and contaminated clothing thoroughly after handling • Do not eat, drink or smoke when using this product • Wear protective gloves, protective clothing, eye, and face protection • Avoid release to the environment GHS - Precautionary Statement(s) - Response • IF SWALLOWED: Rinse mouth. Do NOT induce vomiting • IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell • IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water/shower • IF EXPOSED (skin/eye): Immediately call a POISON CENTER OR PHYSICIAN • Specific treatment for skin contact (see First Aid information on product label and/or Section 4 of the SDS) • Wash contaminated clothing before reuse • IF EXPOSED (skin): Immediately call a POISON CENTER OR LICENSED HEALTH CARE PROVIDER • IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing • IF INHALED: Immediately call a POISON CENTER OR PHYSICIAN • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing • IF IN EYES: Immediately call a POISON CENTER or physician • Get medical advice/attention if you feel unwell • Absorb spillage to prevent material damage • Collect spillage • In case of fire: Use large amounts of water to extinguish GHS - Precautionary Statement(s) -Storage • Store in secure manner • Store in corrosive resistant container with a resistant inner liner GHS - Precautionary Statement(s) - Disposal • Dispose of contents and container in accordance with applicable local, regional, national, and/or international regulations Physical Hazards Not Otherwise Classified • NFPA Class 2 Oxidizer(Class 2 Oxidizers will increase the burning rate of combustible materials with which they come in contact. In addition, they may cause spontaneous ignition when in contact with a combustible material) Hazard Not Otherwise Classified (HNOC)-Health • May be harmful in contact with skin • Potential endocrine disruptor See Section 11: TOXICOLOGICAL INFORMATION SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Print date: 01-Sep-2020 4 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July Component CAS Number Percent[%7 Water 7732-18-5 68-76 Sodium Chlorite 7758-19-2 24.25-25.75 Sodium Chloride 7647-14-5 1 -5 SECTION 4. FIRST AID MEASURES INHALATION: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF INHALED: Call a POISON CENTER OR LICENSED HEALTH CARE PROVIDER if you feel unwell. If breathing is difficult, oxygen should be administered by qualified personnel. SKIN CONTACT: IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. See specific treatment for skin contact below in this Section Under"Notes to Physicians". GET MEDICAL ATTENTION IMMEDIATELY. EYE CONTACT: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF EXPOSED (eyes): Immediately call a POISON CENTER OR LICENSED HEALTH CARE PROVIDER. GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: IF SWALLOWED: Immediately call a POISON CENTER OR LICENSED HEALTH CARE PROVIDER. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. See additional information in "Notes to Physician" below in this Section. GET MEDICAL ATTENTION IMMEDIATELY. Most Important Symptoms/Effects (Acute and Delayed): Acute Symptoms/Effects: Inhalation (Breathing): Breathing (Inhalation): Inhalation of airborne material may cause irritation, redness of upper and lower airways, coughing, laryngeal spasm and edema, shortness of breath, bronchio-constriction, and possible pulmonary edema. Severe and permanent scarring may occur. The pulmonary edema may develop several hours after a severe acute exposure. Skin: Skin Corrosion. Skin exposure to gas or liquid may cause redness, irritation, burning sensation, swelling, blister formation, first, second, or third degree burns. Eye: Serious Eye Damage. Exposure to eyes may cause irritation and burns to the eye-lids, conjunctivitis, corneal edema, and corneal burn. Significant and prolonged contact may cause damage to internal eye structures. Ingestion (Swallowing): Ingestion: Exposure by ingestion may cause irritation, nausea, and vomiting. Oxidation may cause significant metabolic issues such as: methemogobinemia, hemolysis, and intravascular coagulation and renal failure. Delayed Symptoms/Effects: - Repeated and prolonged skin contact may cause a dermatitis Protection of First-Aiders: Protect yourself by avoiding contact with this material.Avoid contact with skin and eyes. Do not ingest. Use personal protective equipment. Refer to Section 8 for specific personal protective equipment recommendations.At minimum,treating personnel should utilize PPE sufficient for prevention of bloodborne pathogen transmission. Print date: 01-Sep-2020 5 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July Notes to Physician: Treat as a corrosive due to the pH of this material. For prolonged exposures and significant exposures, consider delayed injury to exposed tissues. There is no specific antidote. Treatment is supportive care. Follow normal parameters for airway, breathing, and circulation. Ingestion of even small amounts of solution should be closely monitored for methemoglobinemia, hemolysis, and glutathione depletion, followed by renal failure.This chemical acts similarly to its related compound chlorate, and produces a drug induced G6PD deficiency. Methylene blue has not been reported as effective. Consult the PubMed Case Report PMID 22996135 for the case description and treatment utilized. Chlorine dioxide vapors are emitted when this product contacts acids or chlorine. If these vapors are inhaled, monitor patient closely for delayed development of pulmonary edema which may occur up to 48-72 hours post-inhalation. Following ingestion, neutralization and use of activated charcoal is not indicated. In vitro studies have shown that activated charcoal does not adsorb chlorate/chlorite ions. The benefit of decontamination after ingestion is not certain and not recommended. Interaction with Other Chemicals Which Enhance Toxicity: Mixing with ammonia, acids, detergents, or organic matter will release chlorinated compounds, which are irritating to eyes, lungs, and mucus membranes. Medical Conditions Aggravated by Exposure: May aggravate preexisting conditions such as:. Eye disorders that decrease tear production or have reduced integrity. Skin disorders that compromise the integrity of the skin. Respiratory conditions including asthma and other breathing disorders. Ingestion may induce G6PD deficiency, hemolysis and renal failure. G6PD deficiency, hemoglobinopathies, renal compromise, and conditions causing hypoxia may be aggravated by ingestion of this material. SECTION 5. FIRE-FIGHTING MEASURES Fire Hazard: According to NFPA 400, this material is classified as a Class 2 Oxidizer. Class 2 Oxidizers will increase the burning rate of combustible materials with which they come in contact. In addition, they may cause spontaneous ignition when in contact with a combustible material. Avoid evaporation to dryness. Dried material can ignite upon contact with combustibles. Explosive properties: This product may represent an explosion hazard if it contacts acids, chlorine, or organic materials (Refer to Sections 7 and 10). Extinguishing Media: Use extinguishing agents appropriate for surrounding fire. Water is the only effective extinguisher of sodium chlorite. Unsuitable Extinguishing Media: Water is the only effective extinguisher of sodium chlorite. Unusual Hazards: Do not allow sodium chlorite solutions to evaporate to dryness; this product becomes a fire or explosion hazard if allowed to dry and can ignite in contact with combustible materials. Fire Fighting: Wear NIOSH approved positive-pressure self-contained breathing apparatus. Consider evacuation of personnel located downwind. Keep unnecessary people away, isolate hazard area and deny entry. Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Flood with fine water spray.Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Hazardous Combustion Products: Chlorine; Oxides of sodium Print date: 01-Sep-2020 6 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev.Date: 01-Sep-2020 Supersedes Date: 2016-12-July Sensitivity to Mechanical Impact: Not sensitive. Sensitivity to Static Discharge: Not sensitive. Lower Flammability Level (air): Not flammable Upper Flammability Level (air): Not flammable Flash point: Not applicable Auto-ignition Temperature: Not applicable GHS: PHYSICAL HAZARDS: -Oxidizing Liquid-GHS Category 3: May intensify fire; oxidizer - May be corrosive to metals Physical Hazards Not Otherwise Classified - NFPA Class 2 Oxidizer (Class 2 Oxidizers will increase the burning rate of combustible materials with which they come in contact. In addition, they may cause spontaneous ignition when in contact with a combustible material) SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Isolate hazard area and deny entry. Keep unnecessary and unprotected personnel from entering the area.Avoid contact with skin and eyes. If material is allowed to dry, DO NOT make airborne. DO NOT breathe dust. Wear appropriate personal protective equipment recommended in Section 8 of the SDS. Personal Protective Equipment: Cleanup personnel must wear proper protective equipment. For Unknown Concentrations or exposures above IDLH (Immediately Dangerous to Life or Health)- Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. See section 8 for information on personal protective equipment. Emergency Procedures: Evacuate unnecessary personnel and eliminate all sources of ignition. For other than minor leaks, immediately implement predetermined emergency plan. Restrict access to the area until cleanup is complete. Stop the release if it can be done safely from a distance. Prevent material and runoff from entering sewers and waterways if it can be done safely well ahead of the release. Sodium chlorite may represent an explosion hazard if it contacts acids or chlorine. If such contact is possible, evacuation procedures must be placed into effect. Cleanup personnel must wear proper protective equipment. Notify all downstream water users of possible contamination. Environmental Precautions: This material is harmful to aquatic life. This material is alkaline and may raise the pH of surface waters with low buffering capacity. Keep out of water supplies and sewers. Releases should be reported, if required, to appropriate agencies. See Section 12 for additional ecological information. Methods and Materials for Containment, Confinement, and/or Abatement: Contain spill. Spilled materials may be absorbed using non-combustible and non-organic commercial absorbents. Dampen and scoop spilled material into clean, dedicated equipment. Every attempt should be made to avoid mixing spilled material with Print date: 01-Sep-2020 7 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July other chemicals or debris when cleaning up. Keep collected material damp and put into drums. Dried material can ignite upon contact with combustibles. Dispose of promptly. Dispose of in accordance with all applicable regulations. Recovery: Liquid sodium chlorite solutions can be absorb in vermiculite, dry sand or earth and place in corrosive-resistant containers. Contact OxyChem Technical Service for confirmation of other types of absorbents before utilizing. Neutralization: Due to the reactivity of sodium chlorite, neutralization for disposal purposes should be avoided whenever possible. Sodium chlorite neutralization procedures are available by contacting OxyChem Technical Service Department at 800-733-1165 option #1. Sodium chlorite neutralization procedures must be carried out ONLY by properly trained personnel wearing appropriate personal protective equipment and ONLY after thoroughly reviewing the neutralization procedures with manufacturer. Final Disposal: Runoff may pollute waterways. If sodium chlorite is spilled or becomes a waste, it must be disposed of in accordance with local, state, and Federal regulations by a NPDES permitted out-fall or in a permitted hazardous waste treatment, storage, and disposal facility. For waste disposal, see section 13. Additional Disaster Prevention Measures: Keep away from water supplies and sewers. Do not use combustible absorbents such as rags, sawdust, and other natural organic sorbents. SECTION 7. HANDLING AND STORAGE Handling: Precautions for Safe Handling: Do not contaminate sodium chlorite with incompatible materials such as dirt, organic matter, oxidizers, reducing agents, chemicals, soap products, solvents, acids, paint products, or combustible materials. Do not store or transport sodium chlorite with incompatible materials. Contamination may start a chemical reaction with generation of heat, liberation of hazardous gases (chlorine dioxide a poisonous, explosive gas), and possible fire and explosion. Triple rinse empty containers thoroughly with water and dispose of in accordance with label instructions. Technical measures/precautions: All instrumentation should be designed to prevent possible solution freezing in the instrument. Greaseless lubricants should be used in mechanical equipment where there is a potential for leaks or spills. Pumps should not be operated against closed valves as this may result in heating solution above it decomposition temperature. Other precautions: This material is a more severe corrosive and oxidizer when dry. This material's pH and oxidative action contribute to its health and physical hazards. Prevention of contact: Do not breathe dust or spray mist. Wash skin and contaminated clothing thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves, protective clothing, eye, and face protection. Avoid contact with incompatible materials. Avoid release to the environment. Storage: Safe Storage Conditions: Store and handle in accordance with all current regulations and standards. (NFPA Oxidizer Class 2). Store in tightly closed, labeled containers away from combustible materials. Store in a cool, dry area. Store in a well-ventilated area. Store below 212°F (100°C). Avoid exposure to sunlight or ultraviolet light. Keep separated from incompatible substances (see below or Section 10 of the Safety Data Sheet). Sodium chlorite Print date: 01-Sep-2020 8 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev.Date: 01-Sep-2020 Supersedes Date: 2016-12-July solutions exceeding 30%concentration have a greater potential to crystallize at ambient temperatures. Normally, these products should be diluted prior to storage. Where bulk storage of concentrated solutions is required,the tank must be placed in a temperature-controlled location to ensure that the product is maintained at a temperature above its crystallization point. Direct heat should not be applied to the storage tank. Technical measures: All equipment purchased for handling and storing sodium chlorite solutions should be verified by the manufacturer or vendor to be suitable for use with sodium chlorite. Use appropriate containment to avoid environmental contamination. The storage area should not be exposed to direct sunlight or ultraviolet light. It should be fire resistant and have an effective sprinkler system with good ventilation. Do not allow solution to evaporate to dryness; this product becomes a fire or explosion hazard if allowed to dry and can ignite in contact with combustible materials. Storage conditions should comply with the requirements established by the National Fire Protection Association's NFPA 1 —Uniform Fire Code and/or NFPA 400—Hazardous Materials Code and/or the International Code Council's (ICC) International Fire Code. Since both NFPA and ICC codes are used throughout the U.S., consult with local fire departments to determine which codes apply. Incompatible Substances: Acids, reducing agents, combustible material, oxidizing agents, hypochlorite, organic solvents and compounds, garbage, dirt, organic materials, household products, chemicals, soap products, paint products, vinegar, beverages, oils, pine oil, dirty rags, sulfur-containing rubber, or any other foreign matter. Packaging Material: Any containers used to store sodium chlorite solutions should be constructed of one of the following materials: 1. Fiberglass reinforced polyester with Hetron 922 resin or equivalent, color natural,with UV protection, and no internal insulation 2. High density polyethylene(HDPE) 3. Titanium. Additional Information: GHS: PHYSICAL HAZARDS: -Oxidizing Liquid-GHS Category 3: May intensify fire; oxidizer -May be corrosive to metals Physical Hazards Not Otherwise Classified - NFPA Class 2 Oxidizer(Class 2 Oxidizers will increase the burning rate of combustible materials with which they come in contact. In addition,they may cause spontaneous ignition when in contact with a combustible material) SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION REGULATORY EXPOSURE LIMIT(S): This product does not contain any components that have regulatory occupational exposure limits(OEL's). NON-REGULATORY EXPOSURE LIMIT(S): This product does not contain any components that have advisory(non-regulatory)occupational exposure limits (OEL's); however,the manufacturer has established internal Recommended Exposure Level(s) [REL(s)]as noted below. Recommended Exposure Limits(REL's) are non-regulatory occupational exposure limits that the manufacturer has established based on health effects data. Print date: 01-Sep-2020 9 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July Component OXY REL OXY REL OXY REL 8 hr TWA STEL Ceiling Sodium Chlorite 1 mg/rn3 Not applicable Not applicable 7758-19-2 (24.25-25.75%) ENGINEERING CONTROLS: Use only in well-ventilated areas. Provide local exhaust ventilation where vapors, mist or aerosols may be generated. Where sodium chlorite dust may be present, ventilation of the work area should be accomplished as necessary to maintain concentrations in air below 1 mg/m3. PERSONAL PROTECTIVE EQUIPMENT: Eye Protection: Wear chemical safety goggles. Where splashing or spraying is possible, use a face-shield in addition to chemical protective goggles. Provide an emergency eyewash fountain and quick drench shower in the immediate work area. Skin and Body Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron,or full body suit will depend on the task. Remove contaminated clothing immediately, wash skin area with water, and launder clothing before reuse or dispose of properly. Clothing should be rinsed with water before disposal. Hand Protection: Wear appropriate chemical resistant gloves. Consult a glove supplier for assistance in selecting an appropriate chemical resistant glove. Protective Material Types: Neoprene Respiratory Protection: A NIOSH approved full-face respirator equipped with N95(dust, fume, mist)cartridges may be permissible when symptoms have been observed that are indicative of overexposure. If chlorine or chlorine dioxide is present, an acid gas cartridge is also required.An approved self-contained breathing apparatus operated in the pressure demand mode or an airline respirator with escape pack is required when an air purifying respirator is not adequate or for spills/emergencies of unknown concentrations. A respiratory protection program that meets 29 CFR 1910.134 must be followed whenever workplace conditions warrant use of a respirator. HYGIENE MEASURES: Obtain proper training prior to use. An emergency eye wash fountain and quick drench shower should be provided in the immediate work area. Good housekeeping practices are important where sodium chlorite is used.All spills should be contained and immediately recovered or flushed with water into a chemical sewer or a segregated holding tank or pond provided for the specific purpose of neutralization. Sodium chlorite must never be flushed to sanitary sewer or other outlet connecting to waterways to uncontrolled runoff streams. Contact local and federal authorities for applicable regulations. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Pale, yellow Odor: Slight chlorine odor Molecular Weight: 90.45 Molecular Formula: NaCIO2 Print date: 01-Sep-2020 10 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev.Date: 01-Sep-2020 Supersedes Date: 2016-12-July Chemical Family: Sodium Chlorite Solution pH: >12 @ 25°C Melting Point/Range: Not applicable to liquids Freezing Point/Range: No data available Flash point: Not applicable Vapor Pressure: No data available Vapor Density(air=1): No data available Relative DensitylSpecific Gravity(water=l): 1.1 to 1.3 @ 25°C Density: 11.1 lbs/gal @ 35°C; 10.1 lbs/gal @ 25°C Water Solubility: Soluble Partition Coefficient(n-octanol/water): No data available Auto-ignition Temperature: Not applicable Odor Threshold [ppm]: No data available Evaporation Rate(ether=l): No data available Crystallization Temperature: -8°C (17.6°F) Volatility: 59-85% by volume Flammability(solid, gas): Not applicable Lower Flammability Level (air): Not flammable Upper Flammability Level (air): Not flammable Viscosity: No data available SECTION 10. STABILITY AND REACTIVITY Chemical Stability: Stable at normal temperatures and pressures. Reactivity: Not reactive under normal temperatures and pressures. Possibility of Hazardous Reactions: Avoid heat, flames, sparks and other sources of ignition.Avoid evaporation to dryness. Dried material can ignite upon contact with combustibles. Avoid contamination with foreign materials. Avoid exposure to sunlight or ultraviolet light. Conditions to Avoid (e.g., static discharge, shock, or vibration): Avoid mechanical shock or impact, if contaminated. Incompatible Substances: Acids, reducing agents, combustible material, oxidizing agents, hypochlorite, organic solvents and compounds, garbage, dirt, organic materials, household products, chemicals, soap products, paint products, vinegar, beverages, oils, pine oil, dirty rags, sulfur-containing rubber, or any other foreign matter. Hazardous Decomposition Products: Chlorine dioxide is formed on contact with acids,Thermal decomposition products include chlorine and oxides of sodium. Hazardous Polymerization: Will not occur. SECTION 11. TOXICOLOGICAL INFORMATION Print date: 01-Sep-2020 11 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July POTENTIAL HEALTH EFFECTS: ACUTE TOXICITY: Eye contact: Causes serious eye damage. Eye exposures may cause burns to the eye lids, conjunctivitis, corneal edema, and corneal burn. May cause permanent eye damage including blindness. Significant and prolonged contact may cause damage to the internal eye structures. Skin contact: Causes severe skin burns and eye damage. May cause redness, irritation, burning sensation, swelling, blister formation,first, second, or third degree burns. Acute dermal toxicity was dependent on the product concentration and its physical state. The most concentrated existing form(80%) induced severe cutaneous reactions and necrosis, which may have enhanced the irritant properties and systemic availability of the product leading to an LD50 of 134 mg/kg body weight. Conversely, the 31% solution induced at most mild skin irritation thus limiting the systemic passage of the product to the blood and leading to an LD50 higher than 2000 mg/kg body weight. Dermal absorption of a 30% liquid solution ranges approximately 5- 10%. Inhalation: Inhalation may cause coughing, irritation (possibly severe), redness of upper and lower airways, shortness of breath, chemical burns and possibly pulmonary edema. Pulmonary edema may develop several hours after a severe acute exposure. Ingestion: Harmful if swallowed. Ingestion may cause irritation, nausea, and vomiting. Causes significant metabolic issues through oxidation. May induce methemoglobinemia, hemolysis, and intravascular coagulation and renal failure. CHRONIC TOXICITY: Sodium chlorite has produced hemolytic anemia in several animal species at concentrations of 100 mg/L or higher. In a subchronic study using rats, hematological alterations included decreased erthrocyte counts, hemoglobin levels, and hemacrit. Methemoglobin levels decreased in females, but increased in males. There is no evidence of kidney effects in humans; however, in animal studies with sodium chlorite, there is limited evidence of kidney effects. Repeated and prolonged skin contact may result in dermatitis. SIGNS AND SYMPTOMS OF EXPOSURE: Signs and symptoms of exposure vary, and are dependent on the route of exposure, degree of exposure, and duration of exposure. Inhalation (Breathing): Breathing (Inhalation): Inhalation of airborne material may cause irritation, redness of upper and lower airways, coughing, laryngeal spasm and edema, shortness of breath, bronchio-constriction, and possible pulmonary edema. Severe and permanent scarring may occur. The pulmonary edema may develop several hours after a severe acute exposure. Skin: Skin Corrosion. Skin exposure to gas or liquid may cause redness, irritation, burning sensation, swelling, blister formation,first, second, or third degree burns. Eye: Serious Eye Damage. Exposure to eyes may cause irritation and burns to the eye-lids, conjunctivitis, corneal edema, and corneal burn. Significant and prolonged contact may cause damage to internal eye structures. Ingestion (Swallowing): Ingestion: Exposure by ingestion may cause irritation, nausea, and vomiting. Oxidation may cause significant metabolic issues such as: methemogobinemia, hemolysis, and intravascular coagulation and renal failure. Interaction with Other Chemicals Which Enhance Toxicity: Mixing with ammonia, acids, detergents, or organic matter will release chlorinated compounds,which are irritating to eyes, lungs, and mucus membranes. ******************************************************************************************************************************** Print date: 01-Sep-2020 12 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July GHS HEALTH HAZARDS: GHS: CONTACT HAZARD-SKIN: Category 1 B-Causes severe skin burns and eye damage GHS: CONTACT HAZARD-EYE: Category 1 -Causes serious eye damage GHS: ACUTE TOXICITY-ORAL: Category 4- Harmful if swallowed GHS: ACUTE TOXICITY-DERMAL: Category 5 - May be harmful in contact with skin GHS: TARGET ORGAN TOXICITY(REPEATED EXPOSURE): Category 2- May cause damage to blood, spleen, and stomach through prolonged or repeated exposure TOXICITY DATA: PRODUCT TOXICITY DATA: . LD50 Oral: LD50 Dermal: LC50 Inhalation: 389- 1800 mg/kg (Rat) > 2 gm/kg skin-rabbit 0.58 mg/L (4 hr-Rat) COMPONENT TOXICITY DATA: The component toxicity data is populated by the LOLI database and may differ from the product toxicity data given. Component Oral LD50 Dermal LD50 Inhalation LC50 Sodium Chlorite 165 mg/kg (Rat) 107.2 mg/kg (Rabbit) 230 mg/m3(4-h Rat) Eye Irritation/Corrosion: The product is classified as causing serious eye injury(Category 1, H318), according to criteria of the GHS. Skin Irritation/Corrosion: This product is classified as causing severe skin burns (Category 1, H314), according to GHS classification criteria. Skin Absorbent/Dermal Route: May be harmful in contact with skin. Dermal absorption of a 30% liquid solution ranges approximately 5- 10%. RESPIRATORY OR SKIN SENSITIZATION: Not classified as a skin or respiratory sensitizer per GHS criteria. CARCINOGENICITY: There is inadequate evidence for the carcinogenicity of sodium chlorite in experimental animals. No data were available from studies in humans on the carcinogenicity of sodium chlorite. This product is not classified as a carcinogen by NTP, IARC or OSHA. Not classified as a carcinogen per GHS criteria. SPECIFIC TARGET ORGAN TOXICITY(Single Exposure): The substance is not classified as a specific target organ toxicant after single exposure per GHS criteria. SPECIFIC TARGET ORGAN TOXICITY(Repeated or Prolonged Exposure): This product is classified as GHS Category 2 and may cause damage to blood, spleen, and stomach through prolonged or repeated exposure. INHALATION HAZARD: Inhalation is not likely from vapors due to low vapor pressure; however, if mists are inhaled may cause respiratory tract irritation. Its action in the respiratory tract is due to its strong oxidizing capability. Symptoms of pulmonary congestion and edema may develop after a latency period of several hours following severe acute exposure to mists. GERM CELL/IN-VITRO MUTAGENICITY: Not classified as a mutagen per GHS criteria. Sodium chlorite has tested positive in some studies. The significance of these test results for human health is unclear because the oxidizing effects of the chlorite or salting effects of sodium may significantly affect the ability of the tests to accurately detect mutagens. Print date: 01-Sep-2020 13 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July REPRODUCTIVE TOXICITY: Not classified as a reproductive toxin per GHS criteria. There is limited evidence of male reproductive effects in animal studies. DEVELOPMENTAL TOXICITY: Not classified as a developmental or reproductive toxin per GHS criteria. Observations in animal studies include decreased serum levels of thyroid hormones in offspring. ASPIRATION HAZARD: Not classified as an aspiration hazard per GHS criteria. TOXICOKINETICS: The time taken to absorb 50%of the dose for sodium chlorite was 3.5± 1.06 hours. The absorption rate constant was 0.198±0.06/hour. The time taken to eliminate 50% of the dose from the plasma when detected as 36CI was 35.2±3.0 hours. After 72 h, radioactivity from chlorite was found at the highest level in the plasma, followed by stomach,testes, skin, lung, duodenum, kidney, carcass, spleen, ileum, bone marrow and liver. In blood, chlorite levels were distributed evenly between plasma and packed cells. For sodium chlorite, 87 and 13% of initial dose(36-CI)was found in urine and feces, respectively. 36-CI was not detected in expired air throughout the 72 hour time period. Chloride, chlorite and chlorate were found in rat urine 72 hours after the administration. The major metabolite was chloride, representing 31.6% of the initial dose of chlorite. METABOLISM: May metabolize to form elevated chloroform levels in the liver and brain but not in blood. BIOLOGICAL DISTRIBUTION: See Toxicokinetics above. PATHOGENICITY AND ACUTE INFECTIOUSNESS (ORAL, DERMAL,AND INHALATION): Not applicable. ENDOCRINE DISRUPTOR: Sodium chlorite is listed on The Endocrine Disruptors Exchange's (TEDX) List of Potential Endocrine Disruptors database of chemicals with the potential to affect the endocrine system, Every chemical on the TEDX List has one or more verified citations published, accessible, primary scientific research demonstrating effects on the endocrine system. NEUROTOXICITY: Not Available. IMMUNOTOXICITY: Not available. Hazard Not Otherwise Classified (HNOC)-Health • May be harmful in contact with skin • Potential endocrine disruptor SECTION 12. ECOLOGICAL INFORMATION ECOTOXICITY (EC, IC, and LC): Ecotoxicity-Available LOLI Data for Components: Component: Freshwater Fish: invertebrate Algae Toxicity: Other Toxicity: Toxicity: Sodium Chlorite *LC50 Brachydanio *EC50 Daphnia No data available No data available rerio: 100-500 mg/L magna: 0.026 mg/L 96h static*LC50 48h *EC50 Daphnia Lepomis magna: 0.012-0.018 macrochirus: 100 mg/L 48h *EC50 Print date: 01-Sep-2020 14 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev.Date: 01-Sep-2020 Supersedes Date: 2016-12-July mg/L 96h static Daphnia magna: 0.25 *LC50 Oncorhynchus -0.33 mg/L 48h mykiss: 100 mg/L 96h static Sodium Chloride *LC50 Lepomis *EC50 Daphnia No data available *LC50 Eisenia foetida macrochirus: 5560- magna: 340.7-469.2 (48 h filter paper)0.1 6080 mg/L 96h mg/L 48h*EC50 - 1 mg/cm2 flow-through *LC50 Daphnia magna: Lepomis 1000 mg/L 48h macrochirus: 12946 mg/L 96h static *LC50 Pimephales promelas: 6020- 7070 mg/L 96h static *LC50 Pimephales promelas: 6420- 6700 mg/L 96h static *LC50 Oncorhynchus mykiss: 4747-7824 mg/L 96h flow-through *LC50 Pimephales promelas: 7050 mg/L 96h semi-static Sodium Chlorate *LC50 Pimephales *EC50 Daphnia No data available *LC50 Eisenia foetida promelas: 13500 magna: 1093 mg/L (14 Days soil dry mg/L 96h*LC50 24h weight)>750 mg/kg Oncorhynchus mykiss: 1750 mg/L 96h *LC50 Oncorhynchus mykiss:4200 mg/L 24h *LC50 Cyprinus carpio: 7090 mg/L 96h Aquatic Toxicity: LC50 Rainbow trout=290 mg/I as 80% NaCIO2 (96 hour) LC50 Bluegill = 265-310 mg/I as 80% NaCIO2 (96 hour) LC50 Sheepshead minnow=62-90 ppm(96 hour). Invertebrate Toxicity: LC50 Daphnia Magna= 0.29 mg/L as 80% NaCIO2 (48 hour) Other Toxicity: LD50 Mallard duck= 0.49-1.00g/kg as 80% NaCIO2 (gavage) LD50 Bob White quail = 0.39-0.66 g/kg as 80% NaCIO2 (gavage) Sodium chlorite in the diet of birds was not acutely toxic. Eight-day dietary LC50's in the Mallard duck and Bob White quail were > 5,000 ppm FATE AND TRANSPORT: Print date: 01-Sep-2020 15 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July PERSISTENCE: This material will eventually degrade to sodium chloride. BIODEGRADATION: This material is inorganic and not subject to biodegradation; however, chlorite ions are reduced by some bacteria under anaerobic conditions. Sodium chlorite is a strong oxidizing agent and under proper reducing conditions is readily reduced to chloride, and to a lesser extent, chlorate. In strong acidic conditions, chlorite can change into chlorine dioxide. BIOCONCENTRATION: This material will not bioaccumulate. BIOACCUMULATIVE POTENTIAL: Bioaccumulation in aquatic species test does not need to be conducted as the substance has a low potential for bioaccumulation (a log Kow< 3) and is an inorganic substance. MOBILITY IN SOIL: Not applicable. SECTION 13. DISPOSAL CONSIDERATIONS Waste from material: Dispose in accordance with all applicable regulations. Do not put product, spilled product, or filled or partially filled containers into the trash or waste compactor. Contact with incompatible materials could cause a reaction and fire. Contact Technical Service to obtain neutralization instructions. Sodium chlorite is toxic to fish and aquatic organisms. Keep out of water supplies and sewers. If sodium chlorite is spilled or becomes a waste, it must be disposed of in accordance with local, state, and Federal regulations by a NPDES permitted out-fall or in a permitted hazardous waste treatment, storage, and disposal facility. Container Management: Containers are non-refillable. Do not reuse or refill containers. Offer for recycling if available. Offer for reconditioning if appropriate. Triple rinse or pressure rinse container promptly after emptying. Triple rinse containers 5-gallons or smaller as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container'/4 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Triple rinse containers larger than 5 gallons as follows: Empty remaining contents into application equipment or a mix tank. Fill the container'/4 full with water. Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Repeat this procedure two more times. Pressure rinse as follows: Empty the remaining contents into application equipment or a mix tank and continue to drain for 10 seconds after the flow begins to drip. Hold container upside down over application equipment or mix tank or collect rinsate for later use or disposal. Insert pressure rinsing nozzle in the side of the container, and rinse about 40 PSI for at least 30 seconds. Drain for 10 seconds, after the flow begins to drip. Container rinsate must be disposed of in compliance with applicable regulations. Contaminated Material: Dispose according to appropriate regulations. Print date: 01-Sep-2020 16 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July SECTION 14. TRANSPORT INFORMATION LAND TRANSPORT U.S. DOT 49 CFR 172.101: UN NUMBER: UN1908 PROPER SHIPPING NAME: Chlorite solution HAZARD CLASS/ DIVISION: 8 PACKING GROUP: II LABELING REQUIREMENTS: 8 MARINE POLLUTANT: Yes Special provisions for A3; A6; A7; B2; IB2; N34; T7; TP2; TP24. transport: Packaging Exceptions 154. Non-bulk Packaging: 202, Bulk Packaging: 242. CANADIAN TRANSPORTATION OF DANGEROUS GOODS: UN NUMBER: UN1908 SHIPPING NAME: Chlorite solution CLASS OR DIVISION: 8 PACKING/RISK GROUP: II LABELING REQUIREMENTS: 8 CAN. MARINE POLLUTANT: Marine Pollutant MARITIME TRANSPORT(IMO/ IMDG) UN NUMBER: UN1908 PROPER SHIPPING NAME: Chlorite Solution HAZARD CLASS / DIVISION: 8 Packing Group: II LABELING REQUIREMENTS: 8 MARINE POLLUTANT: Marine Pollutant AIR TRANSPORT(ICAO/ IATA) Special Instructions CAO: IATA Certificate for shipping personnel is required Transport in bulk according to Annex II of MARPOL 73178 and the IBC Code Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code. SECTION 15. REGULATORY INFORMATION U.S. REGULATIONS Print date: 01-Sep-2020 17 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. SARA EHS Chemical (40 CFR 355.30) Not regulated. EPCRA SECTIONS 311/312 HAZARD CATEGORIES (40 CFR 370.10): Acute Health Hazard, Chronic Health Hazard, Fire Hazard SARA HAZARD CATEGORIES ALIGNED WITH GHS (2018): Health Hazard-Acute Toxin (any route of exposure) Health Hazard-Skin Corrosion or Irritation Health Hazard-Serious eye damage or eye irritation Health Hazard-Specific Target Organ Toxicity (STOT) Repeat Exposure(RE) Health Hazard - HNOC Physical Hazard- Oxidizer(liquid, solid or gas) Physical Hazard- Corrosive to Metal EPCRA SECTION 313(40 CFR 372.65): Not regulated. DEPARTMENT OF HOMELAND SECURITY(DHS)-Chemical Facility Anti-Terrorism Standards(6 CFR 27): Not likely to be regulated based on composition level of component below in formulation Component DHS- DHS-Sabotag DHS-Sabotag OHS-Theft OHS-Theft DHS-Release OHS-Release CWC Toxic Security e Screening e Min.Conc. Screening Min.Conc. Screening Min.Conc. Chemicals: Issues Threshold Threshold Threshold Qnty. Qnty. Qnty. Sodium Chlorate Theft- Not Listed Not Listed 400 lb STQ a commercial Not Listed Not Listed Not Listed 7775-09-9(<0.5) Explosives/Im grade provised Explosive Device Precursors OSHA PROCESS SAFETY(PSM) (29 CFR 1910.119): Not regulated. FIFRA REGULATIONS: Registered pesticide under 40 CFR 152.10, Federal Insecticide, Fungicide and Rodenticide Act(FIFRA). EPA Reg. No. 21164-6 (Akta Klor 25). FIFRA LABELING REQUIREMENTS: -This chemical is a pesticide product registered by the United States Environmental Protection Agency(EPA)and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets(SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. - FIFRA Signal Word- DANGER - Corrosive -Causes irreversible eye damage and skin burns Print date: 01-Sep-2020 18 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev.Date: 01-Sep-2020 Supersedes Date: 2016-12-July - Harmful if inhaled - Harmful if swallowed or absorbed through skin -Avoid breathing vapor or spray mist -Do not get in eyes, on skin, or on clothing -This product is toxic to fish and aquatic organisms - Dry sodium chlorite is a strong oxidizing agent. This product becomes a fire or explosive hazard if allowed to dry. - Mix only into water -Contamination may start a chemical reaction with generation of heat, liberation of hazardous gases(chlorine dioxide a poisonous, explosive gas), and possible fire and explosion - Do not contaminate with garbage, dirt, organic matter, household products, chemicals, soap products, paint products, solvents, acids, vinegar, beverages, oils, pine oil, dirty rags, or any other foreign matter FDA: This material has Generally Recognized As Safe(GRAS)status under specific U.S. Food and Drug Administration (FDA) regulations,for specified applications. Additional information is available from the Code of Federal Regulations, which is accessible on the FDA's website. Only food grade product meets the FDA's Food Safety Modernization Act(FSMA) requirements, and is guaranteed to be produced under all current Good Manufacturing Practices(cGMP) requirements as defined by the FDA. Food grade product is produced in a facility that is accredited as a Safe Quality Food (SQF) Level 2 Facility, certified under the Global Food Safety Initiative (GFSI), and meets the Food Chemical Codex(FCC) requirements. EPA'S CLEAN WATER AND CLEAN AIR ACTS: Component(s) not listed on impacted regulatory lists. NATIONAL INVENTORY STATUS U.S. INVENTORY STATUS: Toxic Substance Control Act(TSCA): Component TSCA Inventory TSCA ACTIVE TSCA 12(b) TSCA-Section TSCA-Section TSCA-Section TSCA-Section LIST 4 5 6 8 Sodium Chlorite Listed ACTIVE Not Listed Not listed Not Listed Not listed Not listed 7758-19-2 Sodium Chloride Listed ACTIVE Not Listed Not listed Not Listed Not listed Not listed 7647-14-5 Sodium Chlorate Listed ACTIVE Not Listed Not listed Not Listed Not listed Not listed 7775-09-9 CANADIAN CHEMICAL INVENTORY: All components of this product are listed on either the DSL or the NDSL. Component DSL NDSL Sodium Chlorite Listed Not Listed 7758-19-2(24.25-25.75) Sodium Chloride Listed Not Listed 7647-14-5(1 -5) Sodium Chlorate Listed Not Listed 7775-09-9(<0.5) STATE REGULATIONS California Proposition 65: This product and its ingredients are not listed on the California Governor's current list of Carcinogens, Reproductive Toxicants, and/or Candidate Carcinogens (Proposition 65), but it may contain trace amounts of impurities that are listed. For additional information, contact OxyChem Customer Relations. Print date: 01-Sep-2020 19 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev. Date: 01-Sep-2020 Supersedes Date: 2016-12-July Component California California California Massachusetts Right Rhode Island Right Proposition 65 Proposition 65 CRT Proposition 65 CRT to Know Hazardous to Know Hazardous Cancer WARNING: List-Male List-Female Substance List Substance List reproductive toxin: reproductive toxin: Sodium Chlorite Not Listed Not Listed Not Listed Listed Not Listed Sodium Chloride Not Listed Not Listed Not Listed Not Listed Not Listed Sodium Chlorate Not Listed Not Listed Not Listed Listed Listed Component New Jersey New Jersey New Jersey- Pennsylvania Pennsylvania Pennsylvania Pennsylvania Right to Know Special Health Environmental Right to Know Right to Know Right to Know Right to Know Hazardous Hazards Hazardous Hazardous Special Special Environmental Substance List Substance List Substance List Substance List Hazardous Hazardous Hazard List Substances Substances Sodium Chlorite 1689 corrosive; Not Listed Listed Not Listed Not Listed Not Listed reactive- second degree Sodium Chloride Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Sodium Chlorate 1688 reactive- Not Listed Listed Not Listed Not Listed Not Listed second degree CANADIAN REGULATIONS This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. Component Canada-CEPA- Canada-NPRI Canada-CEPA- CANADIAN NDSL: Schedule I-List of 2010 Greenhouse CHEMICAL Toxic Substances Gases(GHG)Subject INVENTORY: to Mandatory Reporting Sodium Chlorite Not listed Not Listed Not Listed Listed Not Listed 7758-19-2(24.25-25.75) Sodium Chloride Not listed Not Listed Not Listed Listed Not Listed 7647-14-5(1 -5) Sodium Chlorate Not listed Not Listed Not Listed Listed Not Listed 7775-09-9(<0.5) SECTION 16. OTHER INFORMATION Prepared by: Occidental Chemical Corporation- HES&S Product Stewardship Department Rev. Date: 01-Sep-2020 Reason for Revision: • Scheduled review • Change of company physical address: SEE SECTION 1 • Product Name and/or Trade Name(s) has been revised: SEE SECTION 1 • Updated Customer Service Contact Information: SEE SECTION 1 • Included additional information for other usage that may be restricted and/or prohibited: SEE SECTION 1 • Emergency Overview was revised: SEE SECTION 2 Print date: 01-Sep-2020 20 of 21 M47030- North America - EN AKTA KLOR 25 SDS No.: M47030 Rev.Date: 01-Sep-2020 Supersedes Date: 2016-12-July • GHS Symbol(s) added or changed: SEE SECTION 2 • Changed the GHS classification: SEE SECTION 2 • Modified GHS Hazard and Precautionary Statements: SEE SECTION 2 •Added or revised Hazards Not Otherwise Classified: SEE SECTION 2 •Added Health Hazards Not Otherwise Classified: Section 2 and 11 •The formulation has been revised: SEE SECTION 3 • Updated First Aid Measures: SEE SECTION 4 •Change to "Note to Physician" (added/changed/or deleted): SEE SECTION 4 • Modified Fire Fighting Measure Recommendations: SEE SECTION 5 •Added Physical Hazards Not Otherwise Classified to format: SEE SECTIONS 5&7 • Revised Accidental Release Measures: SEE SECTION 6 • Revised Handling and Storage Recommendations: SEE SECTION 7 • PPE recommendations have been modified: SEE SECTION 8 •Added Hygiene Measures SEE SECTION 8 • Updated Physical and Chemical Properties. SEE SECTION 9 •Toxicological Information has been revised: SEE SECTION 11 • Ecological Information has been modified: SEE SECTION 12 • Updated Disposal Considerations. SEE SECTION 13 • Updated Transportation Information: SEE SECTION 14 • Regulatory Information Changes: SEE SECTION 15 • Revised SARA Hazard Categories 311/312 HAZARD CATEGORIES (40 CFR 370.21): SEE SECTION 15 •Added LOLI tables such as EPA'S Clean Water/Air Act, TSCA status, DHS, PSM, EPCRA, CERCLA, Federal Canadian: SEE SECTION 15 •Added Department of Homeland Security Anti-Terrorism Information: SEE SECTION 15 • Modified SARA Hazard Categories Aligned with GHS (2018): SEE SECTION 15 •WHMIS Classifications were removed from format: SEE SECTION 15 • Updated TSCA Status Table: SEE SECTION 15 IMPORTANT: The information presented herein, while not guaranteed,was prepared by technical personnel and is true and accurate to the best of our knowledge. NO WARRANTY OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE, OR WARRANTY OR GUARANTY OF ANY OTHER KIND, EXPRESSED OR IMPLIED, IS MADE REGARDING PERFORMANCE, SAFETY, SUITABILITY, STABILITY OR OTHERWISE. This information is not intended to be all-inclusive as to the manner and conditions of use, handling, storage, disposal and other factors that may involve other or additional legal, environmental, safety or performance considerations,and Occidental Chemical Corporation assumes no liability whatsoever for the use of or reliance upon this information. While our technical personnel will be happy to respond to questions, safe handling and use of the product remains the responsibility of the customer. No suggestions for use are intended as, and nothing herein shall be construed as, a recommendation to infringe any existing patents or to violate any federal, state, local or foreign laws. OSHA Standard 29 CFR 1910.1200 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling, safety data sheets, training and access to written records. We request that you, and it is your legal duty to, make all information in this Safety Data Sheet available to your employees. End of Safety Data Sheet Print date: 01-Sep-2020 21 of 21